Facile synthesis of cyanogen glycosides (R)-prunasin, linamarin and (S)-heterodendrin
1998
Nakajima, N. (Toyama Prefectural Univ., Kosugi (Japan). Faculty of Engineering) | Ubukata, M.
A facile synthetic route is described to cyanogenic glycoside (R)-prunasin, linamarin and (S)-heterodendrin from O-(2,3,4,6-tetra-O-acetyl-alpha-D-glucopyranosyl) trichloroacetimidate and the corresponding alpha-hydroxyamides by a 3-step reaction of glycosylation, cyanohydrin formation by dehydration of carboxamides, and deprotection
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