Relationships between structure and performance of vulcanisates
1990
Campbell, D. S. | Chapman, A. V.
Available experimental procedures for estimating chemical crosslink density in rubber vulcanisates and the present state of knowledge of the correlation of chemical crosslink structure with properties of natural rubber vulcanisates are critically assessed. Differentiation is made between correlations with technological test data and with chemical constitution. The difficulties associated with quantitative measurement of chemical crosslink density in gum and filled systems are reviewed and the discussion is amplified by specific reference to published work on the rote of polysulphide crosslinks in determining strength properties.
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