Multifunctional Photocatalytic Filter Paper Based on Ultralong Nanowires of the Calcium-Alendronate Complex for High-Performance Water Purification

Semiconductor photocatalysts and membrane separation technology have been widely used in the field of water treatment. Usually, the particles of traditional semiconductor photocatalysts are easy to aggregate, difficult to separate from the liquid phase after photocatalysis, and may even cause secondary pollution. On the other hand, the membrane separation technology is also facing the problem of sharp decreases in removal efficiency and water flux caused by the membrane fouling. However, it is an attractive and promising solution to combine two technologies of photocatalysis and membrane separation for high-performance water treatment. In this work, we have developed the calcium oleate precursor solvothermal method to synthesize ultralong nanowires (UNWs) of Ca-alendronate (Ca-ALN) complex for the first time. Experimental results and data analysis indicate that the as-prepared Ca-ALN ultralong nanowires are an n-type semiconductor with an energy band gap of 3.41 eV. A new type of multifunctional photocatalytic filter paper has been developed based on ultralong nanowires of Ca-ALN complex (Ca-ALN-UNWs) and cellulose fibers (CFs). The as-prepared Ca-ALN-UNW/CF photocatalytic filter paper exhibits multifunctions of photocatalysis, adsorption, and filtration, which can be used for high-performance treatment of the wastewater containing various pollutants such as heavy-metal ions, dyes, antibiotics, and bacteria. The active oxygen species produced by the Ca-ALN-UNW/CF photocatalytic filter paper under light illumination are determined by electron spin resonance, and the energy band gap and photoelectric properties of the material are tested by ultraviolet–visible diffuse reflectance spectroscopy and electrochemical workstation. The pure water flux of the Ca-ALN-UNW/CF photocatalytic filter paper is very high, which can reach 2230.5 L m–² h–¹ under a working pressure of 0.1 MPa. The Ca-ALN-UNW/CF photocatalytic filter paper is promising for various applications such as highly efficient water purification and in the biomedical field.