Electrocatalytic carboxylation of benzyl chlorides at silver cathodes in acetonitrile
2002
Isse, Abdirisak A. | Gennaro, Armando
Silver exhibits powerful electrocatalytic activities towards the reductive carboxylation of benzyl chlorides (RCl): in CO₂-saturated CH₃CN, reduction of RCl occurs at potentials that are about 0.6 V more positive than those of the same process at Hg or carbon electrodes and gives carboxylic acids in good to excellent yields.
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