Aromatic trifluoromethylation catalytic in copper
2009
Oishi, Masahiro | Kondo, Hideaki | Amii, Hideki
Cu(i)-diamine complexes were found to catalyse the trifluoromethylation of aryl iodides. In the presence of a small amount of CuX (X = Cl, Br, I) and 1,10-phenanthroline (phen), the cross-coupling reactions of iodoarenes with trifluoromethylsilanes proceeded smoothly to afford trifluoromethylated aromatics in good yields.
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