Effect of benzoic acid on the removal of 1,2-dichloroethane by a siderite-catalyzed hydrogen peroxide and persulfate system
2016
Li, Shengpin | Li, Mengjiao | Luo, Ximing | Huang, Guoxin | Liu, Fei | Chen, Honghan
Benzoic acid can affect the iron-oxide mineral dissolution and react with hydroxyl radical. This study investigated its effect on 1,2-dichloroethane removal process by siderite-catalyzed hydrogen peroxide and persulfate. The variation of benzoic acid concentrations can affect pH value and soluble iron concentrations; when benzoic acid varied from 0 to 0.5 mmol/L, pH increased while Fe²⁺ and Fe³⁺ concentrations decreased, resulting in 1,2-dichloroethane removal efficiency which decreased from 91.2 to 5.0 %. However, when benzoic acid varied from 0.5 to 10 mmol/L, pH decreased while Fe²⁺ and Fe³⁺ concentrations increased, resulting in 1,2-dichloroethane removal efficiency which increased from 5.0 to 83.4 %.
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