Highly efficient chiral metal cluster systems derived from Ru₃(CO)₁₂ and chiral diiminodiphosphines for the asymmetric transfer hydrogenation of ketones
2002
Zhang, Hui | Yang, Chuan-Bo | Li, Yan-Yun | Donga, Zhen-Rong | Gao, Jing-Xing | Nakamura, Hideaki | Murata, Kunihiko | Ikariya, Takao
The chiral Ru cluster-based catalyst systems generated in situ from Ru₃(CO)₁₂ and chiral diiminodiphosphine tetradentate ligands effected asymmetric transfer hydrogenation of propiophenone in 2-propanol, leading to 1-phenyl-1-propanol in 94% yield and with 96% ee.
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