Investigation of size-dependent properties of sub-nanometer palladium clusters encapsulated within a polyamine dendrimer
2012
Kibata, Takayuki | Mitsudome, Takato | Mizugaki, Tomoo | Jitsukawa, Koichiro | Kaneda, Kiyotomi
This study describes the first example of the investigation of electronic, geometric, and catalytic properties of Pd subnano metal clusters of Pd₄, Pd₈, and Pd₁₆ stabilized by poly(propylene imine) (PPI) dendrimers using XAFS and IR analyses. The relations among these properties are also discussed.
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