Temporal variations in groundwater nitrogen under intensive groundwater/surface-water interaction | Variations temporelles de l’azote des eaux souterraines sous forte interaction entre les eaux souterraines et les eaux de surface Variaciones temporales del nitrógeno en el agua subterránea bajo una intensiva interacción agua subterránea/agua superficial 强烈的地下水—地表水相互作用下地下水氮的季节性变化 Variação temporal do nitrogênio nas águas subterrâneas sob intensa interação água subterrânea/água superficial

Nitrogen (N) pollution in shallow groundwater within the Jianghan Plain—a depositional basin along the Yangtze River in China—is a serious issue affecting the local water supply. There is little concern regarding temporal variation patterns of groundwater N in regions with intensive groundwater/surface-water interactions thus far. In this study, a 2-year field monitoring program and a set of incubation experiments were jointly applied to characterize the seasonal variation mechanisms of groundwater N. Groundwater monitoring suggested that temporal N variations in monitoring wells of 25 and 10-m depth were correlated with fluctuations in water levels, with lower NH₄-N and higher NO₃⁻-N concentrations corresponding to groundwater discharge during the dry season, and with higher NH₄-N and lower NO₃⁻-N concentrations corresponding to groundwater recharge during the wet season. Batch sediment incubation experiments showed that buried organic carbon in sediments from the field site could not promote NH₄-N release, but exogenous organic carbon and oxidant input could catalyze organic N mineralization, resulting in NH₄-N release. Nevertheless, NO₃⁻-N release was limited in all incubations. Thus, the temporal variation patterns could be divided into (1) groundwater N in type-1 wells (25 and 10 m), controlled by the annual reversal of groundwater flow gradient, which determined whether there was input of exogenous organic carbon or oxidants, ultimately affecting organic N mineralization, denitrification and other transformation processes, and (2) groundwater N in type-2 wells (<4 m depth), which showed no significant seasonal variation, implying the process is mainly controlled by surface inputs in the shallower subsurface.