Notizen: Gezielte Synthese von Sulfinato-O–und -S-Komplexen einiger Übergangsmetalle, XVIII1 Synthese eines Sulfinato-O-Komplexes und Ionisationsisomerie bei Palladium(II)2 / Directed Synthesis of Sulfinato-O and -S Complexes of Some Transition Metals, XVIII1. Synthesis of a Sulfinato-O Complex and Ionization Isomerism with Palladium(II)2
2014
Lorenz, Ingo-Peter | Lindner, Ekkehard | Reuther, Wolfgang
The sulfinato-O complex (p-CH₃C₆H₄S(O)O)₂Pd(en) (2a) and its ionization isomer, the ionic compound [Pd(en)₂][p-CH₃C₆H₄SO₂]₂ (2b), are obtained from 1 by ligand addition in dependence of the nature of the solvent. 2 a, b can be transformed into each other reversibly. For 2 a two structural models are discussed. The pseudooctahedral configuration with two bidentate ethylene diamine and two sulfinato-O ligands in trans position seems to be more likely.
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