Catalytic asymmetric hydrogenation to access spiroindane dimethyl acetic acid
2011
He, Shuwen | Shultz, C Scott | Lai, Zhong | Eid, Ronsar | Dobbelaar, Peter H. | Ye, Zhixiong | Nargund, Ravi P.
Asymmetric hydrogenation of achiral spiroindene dimethyl acetic acid 2 with 4% of Ru(II)-Mandyphos in acetone produced (S)-spiroindane dimethyl acetic acid 1 in 86% isolated yield and 96.8:3.2 enantiomeric ratio.
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