Ultrafast Carbon-Carbon Single-Bond Rotational Isomerization in Room-Temperature Solution
2006
Generally, rotational isomerization about the carbon-carbon single bond in simple ethane derivatives in room-temperature solution under thermal equilibrium conditions has been too fast to measure. We achieved this goal using two-dimensional infrared vibrational echo spectroscopy to observe isomerization between the gauche and trans conformations of an ethane derivative, 1-fluoro-2-isocyanato-ethane (1), in a CCl4 solution at room temperature. The isomerization time constant is 43 picoseconds (ps, 10-12 s). Based on this value and on density functional theory calculations of the barrier heights of 1, n-butane, and ethane, the time constants for n-butane and ethane internal rotation under the same conditions are ~40 and ~12 ps, respectively.
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