Contrasting dynamic responses of supported Rh nanoparticles to H₂S and SO₂ and subsequent poisoning of NO reduction by H₂
2003
Newton, Mark A. | Dent, Andrew J. | Diaz-Moreno, Sofia | Fiddy, Steven G. | Jyoti, Bhrat | Evans, John
H₂S induces rapid sulfidation of the Rh nanoparticles at room temperature and completely poisons NO reduction by H₂; SO₂ elicits an equally rapid but subtle modification of nanoparticle structure but has little effect upon NO reduction at 523 K.
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