Chlorobenzene Destruction over Mesostructured CuO and MnO x Co-Modified CeO 2 Catalyst: Activity and Activation Route
2015
He, Chi | Men, Gaoshan | Yu, Yanke | Pan, Hua | Xu, Bitao
Mesostructured CuMnCeO ₓ catalysts were prepared and tested in chlorobenzene destruction. Mn and Cu phases enter CeO₂matrix with a fluorite-like structure to form Cu–Mn–O–Ce solid solution. Both synthesis protocol and metal-doping content affect the metal state, reducibility, and oxygen distribution of composites. The c₀.₁₅c₀.₁₅c₀.₇sample exhibits the highest activity with 90 % of chlorobenzene oxidized at around 250 °C. Enhanced oxygen concentration and mobility, and abundant oxygen vacancy promote the desorption of adsorbed Cl, which guarantees the superior stability of CuMnCeO ₓ . Incorporation of CuO and MnO ₓ effectively inhibits the formation of organic byproducts, such as phenolates, maleates, and o-benzoquinone, especially at elevated temperatures.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library
