Environmentally friendly acetic acid/steam explosion/supercritical carbon dioxide system for the pre-treatment of wheat straw
2021
Zabihi, Samyar | Sharafi, Amir | Motamedi, Hossein | Esmaeilzadeh, Feridun | Doherty, William O. S.
It is well established that pretreatment of lignocellulosic biomass is required to achieve an effective enzymatic saccharification process. At the present time, most of the touted pre-treatment technologies would cause environmental pollution and unsustainable water use for the pretreated material prior to enzymatic saccharification. To address these shortcomings, the pretreatment technology which combines the supercritical CO₂, SC-CO₂ (a green solvent), acetic acid, and steam explosion was used to assess the pretreatment of wheat straw for enzymatic saccharification. The effects of solvent concentration, impregnation temperature and time, pre-treatment time, and temperature, as well as SC-CO₂ pressure, contact time, and temperature, were evaluated. The results identified that at the optimum SC-CO₂ pressure of 18 MPa, the highest amount of reducing sugars (RS) was produced from the cellulosic pulp using Acetic acid/Steam/SC-CO₂ at 200 °C for 30 min, a value 20% more than the pulp produced with the Water/Steam/SC-CO₂. The effectiveness of the pretreatment process was attributed not only to delignification and defibrillation but also to the exposure of the cellulose structure evidenced from the proportion of the β-glycosidic linkages as shown by FTIR. Passing SC-CO₂ after the pretreatment reduces the amounts of fermentation inhibitors and eliminates the use of wash water.
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