Catalytic and regiospecific extradiol cleavage of catechol by a biomimetic iron complex
2013
Chatterjee, Sayanti | Sheet, Debobrata | Paine, Tapan Kanti
An iron(iii)–catecholate complex of a facial tridentate ligand reacts with dioxygen in the presence of ammonium acetate–acetic acid buffer to cleave the aromatic C–C bond of 3,5-di-tert-butylcatechol regiospecifically resulting in the formation of an extradiol product with multiple turnovers.
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