Potential Risk Assessment of Trace Elements and PAHs in Sediment Samples of the Ebro River Basin (Spain)
2013
Veses, Oscar | Mosteo, Rosa | Ormad, Maria P. | Ovelleiro, Jose L.
This study was carried out in order to assess potential toxicity of hazardous pollutants (8 trace elements and 8 polycyclic aromatic hydrocarbons) in 20 sediment samples of the Ebro River basin (Spain) sampled in 2009. Mean-probable effect concentration quotient (m-PECQ) was found to range from 0.03 to 0.79. Two sites were classified as high priority sites in order to take future remediation actions due to their high m-PECQ value (>0.5). Worst-case scenario in equilibrium partitioning approach showed that acid volatile sulfide (AVS) content was greater than total trace element concentration in all samples. However, 4 sediments were classified as degraded due to the high AVS content measured (>50 mmol/kg). Principal component analysis classified the samples according to similar chemical characteristics and revealed that industrial activities are the main source of pollution of the basin.
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