Synthesis and insecticidal activity of nitroguanidine derivatives
1999
Uneme, H. | Iwanaga, K. | Higuchi, N. | Kando, Y. | Okauchi, T. | Akayama, A. | Minamida, I.
Nitroguanidine derivatives with thiazol-5-ylmethyl moieties were prepared and their insecticidal activities against homopterous pests were tested. New synthetic routes for 2-chloro-5-chloromethylthiazole from 2,3-dichloro-1-propene and for substituted nitroguanidines from S-methyl-N-nitroisothiourea were established. Biological evaluation led to a novel insecticide (E)-1-(2-chlorothiazol-5-ylmethyl)-3-methyl-2- nitroguanidine (TI-435) which has a broad activity spectrum and is under development.
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