First intramolecular enantioselective iridium-catalysed allylic aminations
2004
Welter, Carolin | Koch, Oliver | Lipowsky, Gunter | Helmchen, Günter
Enantioselective iridium-catalysed intramolecular allylic aminations, using phosphinooxazolines or phosphorus amidites as ligands, provided ee values of >90%, at a catalyst loading of <0.5 mol-%, and displayed a marked preference for intra- over corresponding intermolecular reactions.
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