Hybrid aminopolymer–silica materials for efficient CO₂ adsorption
2015
López-Aranguren, Pedro | Builes, Santiago | Fraile, Julio | López-Periago, Ana | Vega, Lourdes F. | Domingo, Concepción
The present work focuses on the development of a new eco-efficient chemical method for the polymerization of aziridine to hyperbranched polyethyleneimine (PEI) into mesoporous silica by using compressed CO₂ as a solvent, reaction medium and catalyst. PEI was in situ grafted into MCM-41 and silica gel substrates, with pore diameters of 3.8 and 9.0 nm, respectively. The optimal polymerization conditions were found by varying the reaction pressure (1.0–10 MPa), temperature (25–45 °C) and time (20–400 min). The thermal stability analysis indicated that aminopolymer chains were covalently attached on the amorphous silica surface. The described compressed CO₂ route for the synthesis of high amine content hybrid products (6–8 mmolN g⁻¹) is a very fast method, with processing times in the order of few minutes even at very low working pressures (1.0 MPa), being a step forward in the design of efficient hybrid aminopolymer nanocomposites for CO₂ capture. The adsorptive behavior of the prepared hybrid materials was experimentally established by recording the N₂ (−196 °C) and CO₂ (25, 50 and 75 °C) adsorption isotherms. Results were compared to molecular simulation studies performed using Grand Canonical Monte Carlo for either N₂ or CO₂ adsorbed on amino modified MCM-41, thus helping to elucidate the predominant PEI configuration present in the functionalized materials.
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