Corn husk derived magnetized activated carbon for the removal of phenol and para-nitrophenol from aqueous solution: Interaction mechanism, insights on adsorbent characteristics, and isothermal, kinetic and thermodynamic properties
2019
Mishra, Shubham | Yadav, Swati Singh | Rawat, Shalu | Singh, Jiwan | Koduru, Janardhan Reddy
In this study, waste corn husk was used for the synthesis of an effective adsorbent (cornhusk activated carbon, CHAC) and by treating at two different temperatures, 250 °C (CHAC-250) and 500 °C (CHAC-500) to check adsorption efficiency. The synthesized adsorbents were characterized with the help of scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy, Particle size analysis and x-ray diffraction (XRD), which revealed the different properties of the two adsorbents. The synthesized adsorbents were applied for the removal of phenol and p-nitrophenol (PNP) from aqueous solution. CHAC-500 was more efficient than the CHAC-250. The maximum adsorptions of phenol and PNP by CHAC-500 were ∼96% and ∼94%, respectively, while the maximum adsorptions of phenol and PNP by CHAC-250 were ∼81% and ∼84%, respectively. The adsorption processes were best fitted with the Langmuir adsorption isotherm and the pseudo-second-order kinetic model. The adsorption of phenol was an exothermic process, while that of PNP was an endothermic process, on both adsorbents.
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