Facile fabrication of hybrid titanium(IV) isopropoxide/pozzolan nanosheets (TnS-Pz) of high photocatalytic activity: characterization and application for Cr(VI) reduction in an aqueous solution
2021
Novack, Aline M. | dos Reis, Glaydson S. | Hackbarth, Fabíola V. | Marinho, Belisa A. | Ðolić, Maja B. | Valle, José A. B. | Sampaio, Carlos H. | Lima, Eder C. | Dotto, Guillherme L. | Ulson de Souza, Antônio Augusto | Vilar, Vítor J. P. | Guelli Ulson de Souza, Selene M. A.
This paper presents the synthesis of a hybrid material through the use of natural pozzolan and titanium(IV) isopropoxide using the sol-gel method and its application in the photocatalytic hexavalent chromium reduction. The characterization data indicated a mesoporous material possessing a surface area of 271.7 m² g⁻¹. The morphology studies (SEM and TEM) showed nanosheet hybrid structures. The analysis of DRUV, FTIR, XRD, and Mössbauer spectroscopy provides a different electronic structure of the synthetized material when compared with the originals, proving the hybridization process between pozzolan and titanium(IV) isopropoxide. The photocatalytic reduction of Cr(VI) to Cr(III) using the hybrid material showed a better performance than conventional photocatalysts (precursor and TiO₂-P25). Operational conditions such as chromium initial concentration (0.02–0.20 mM), solution pH (3–6), and type of scavenger (citric or tartaric acid) were evaluated in order to determine the best experimental conditions for the Cr(VI) photoreduction. At their optimum (catalyst load of 15 mg L⁻¹, tartaric acid as scavenger, [scavenger]₀/[Cr(VI)]₀ M ratio = 3:1, pH 3, and 25 °C), the total photoreduction of 0.20 mM Cr(VI) was achieved in 180 min. The novel hybrid materials synthesized from pozzolan and titanium(IV) isopropoxide showed to be a potential catalyst for the Cr(VI) reduction in aqueous solution. Graphical abstract
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