Affecting surface chirality via multicomponent adsorption of chiral and achiral molecules
2014
Guo, Zongxia | De Cat, Inge | Van Averbeke, Bernard | Lin, Jianbin | Wang, Guojie | Xu, Hong | Lazzaroni, Roberto | Beljonne, David | Schenning, Albertus P. H. J. | Feyter, Steven De
Here we report on the apparent reduction in surface chirality upon co-assembling a chiral and achiral molecule into a physisorbed self-assembled monolayer at the liquid/solid interface as revealed by scanning tunneling microscopy (STM). Chiral OPV with achiral thymine gives rise to surface-confined supramolecular diastereomers.
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