Application of biowaste generated by the production chain of pitaya fruit (Hylocereus undatus) as an efficient adsorbent for removal of naproxen in water
2022
Franco, Dison S. P. | da Boit Martinello, Kátia | Georgin, Jordana | Netto, Matias S. | Foletto, Edson Luiz | Piccilli, Daniel G. A. | Silva, Luis F. O. | dos Reis, Glaydson S. | Dotto, Guilherme Luiz
Pharmaceutical compounds are a serious problem in the environment. They cause damage to the aquatic, animal, and human organisms and soon became considered emerging pollutants where their removal is extremely urgent. Among the techniques used, adsorption has been used with success, where several adsorbent materials, including those from residual biomass, have been used to remove these pollutants. In this study, the skins of the pitaya fruit (Hylocereus undatus) productive chain were carbonized with ZnCl₂ to obtain activated carbon and later used in the adsorption of the drug naproxen (NPX) in a batch system. The Freundlich model demonstrated a better adjustment for the equilibrium isotherms. A high adsorption capacity for NPX (158.81 mg g⁻¹) was obtained at 328 K, which can be attributed to the remarkable textural properties of the adsorbent, besides certain functional groups present on its surface. Thermodynamic studies confirmed the endothermic nature of the adsorption process (∆H⁰ = 0.2898 kJ mol⁻¹). The linear driving force model (LDF) presented a good statistical adjustment to the experimental kinetic data. The application of the material in the treatment of simulated wastewater composed of various pharmaceutical drugs and salts was very promising, reaching 75.7% removal. Therefore, it can be inferred that the application of activated carbon derived from pitaya bark is highly promising in removing the NPX drug and treating synthetic mixtures containing other pharmaceutical substances.
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