End-group differentiating ozonolysis of furocoumarins
2014
Malakhov, Mikhail V. | Dubinnyi, Maxim A. | Vlasova, Natalia V. | Zgoda, Victor G. | Efremov, Roman G. | Boldyrev, Ivan A.
Ozonolysis of furocoumarins followed by reductive work-up yields not only common symmetrical dialdehydes, but also o-formylumbelliferones with moderate-to-high yields. Simultaneous formation of both products accounts for the transformation of carbonyl oxides – products of primary ozonide ring opening.
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