Dissipation behavior, residue transfer, and safety evaluation of chlorantraniliprole and indoxacarb during tea growing and brewing by ultrahigh-performance liquid chromatography-tandem mass spectrometry
2022
Xu, Feng | Lu, Zhenyang | Xu, Duo | Lu, Hui | Qiu, Jiuyang | Zha, Xinxin
A reliable and simple analytical method was developed and validated to simultaneously determine chlorantraniliprole and indoxacarb in tea using ultrahigh-performance liquid chromatography-tandem mass spectrometry. The average recoveries of chlorantraniliprole were in the range of 86–110%, with the precision of intraday (n = 5) and interday (n = 15) ranging from 1.9 to 8.4% and from 2.4 to 8.8%, respectively. The average recoveries of indoxacarb were in the range 81–105%, with the precision of intraday (n = 5) and interday (n = 15) ranging from 2.0 to 9.8% and from 2.7 to 9.1%, respectively. The limits of quantification (LOQs) were all 0.01 mg/kg. The results based on the supervised field trials showed that chlorantraniliprole and indoxacarb in two tea samples followed first-order kinetics models with half-lives of 2.2–4.7 days and 2.5–3.5 days, which could be regarded as a moderately degrading pesticide. The terminal residues of chlorantraniliprole and indoxacarb in made tea were below 6.7 and 4.5 mg/kg, respectively, lower than their corresponding maximum residue limits (MRLs) established by several major countries and organizations (50 and 5 mg/kg). The leaching rates of chlorantraniliprole and indoxacarb during the tea brewing ranged from 4.78 to 12.62% and 4.13 to 10.67%, respectively. The chronic intake risk quotient (RQc) values for chlorantraniliprole and indoxacarb were 0.24% and 35.10%, while the acute dietary risk assessment (RQa) value of indoxacarb was 5.8%, which were all much lower than 100%. The results in the present study indicated that the health risk posed by the chlorantraniliprole and indoxacarb mixture pesticides was negligible in tea for consumers at the recommended dosages.
Show more [+] Less [-]AGROVOC Keywords
Bibliographic information
This bibliographic record has been provided by National Agricultural Library
