Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes
2020
Wang, Hui | Zhang, Ge | Zhang, Qian | Wang, Ying | Li, Yanfei | Xiong, Tao | Zhang, Qian
The non-directed hydrosilylation of cyclopropenes with earth-abundant and environmentally benign base metal catalysis was described. This protocol is effective for a wide array of 3,3-disubstituted and 1,2-disubstituted cyclopropenes, and hence provides a facile and straightforward route to synthetically valuable polysubstituted and challenging fully substituted cyclopropylsilanes with high efficiency and diastereoselectivity.
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