Exploring organic and inorganic contaminant histories in sediment cores across the anthropocene: Accounting for site/area dependent factors

Sedimentary records help chronologically identify anthropogenic contamination in environmental systems. This study analysed dated sediment cores from L’Albufera Lake (Valencia, Spain), to assess the occurrence of heavy metals (HMs), polycyclic aromatic hydrocarbons (PAHs), perfluoroalkyl substances (PFASs), organophosphorus flame retardants (OPFRs), pesticides and pharmaceuticals and personal care products (PPCPs). The results evidence the continuing vertical presence of all types of contaminants in this location. The sediment age was difficult to establish. However, the presence of shells together with an historical estimation and the knowledge of sedimentary rates could help. HMs contents are higher in the upper layer reflecting the most recent increase of the industrial and agricultural practices in the area since the middle 20th century. Higher availability index of these HMs in the upper sediment layers is associated with point and diffuse contamination sources in the area. PAHs and OPFRs were homogeneous distributed through the sediments with few exceptions such as phenanthrene in the North and fluoranthene in the South. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) were detected throughout the sediment core while short-chain PFASs (except perfluoropentanoic acid (PFPeA)) were detected only in the top layer. Pesticides and PPCPs showed appreciable down-core mobility. The vertical concentration profiles of organic contaminants did not exhibit a clear trend with depth, then, it is difficult to develop a direct relationship between sediment age and contaminant concentrations, and to elucidate the historical trend of contamination based on dated sediment core. Consequently, linking contaminant occurrence in sediments directly to their historical use is somewhat speculative at least in the conditions of L’Albufera Lake.

This work has been supported by the Grant CIPROM/2021/032 funded by the Conselleria d'Educació, Universitats i Ocupació of the Generalitat Valenciana. Y. Soriano acknowledges her pre-doctoral contract by the grant PRE2019–089042 funded by MCIN/AEI/ 10.13039/501100011033 and by “ESF Investing in your future”. The instrumental used in this study were financed by the project IDFEDER-2021–083 “X-ray of pollution and the effects of the anthropocene/climate change binomial (X pollutants)” action co-financed by the EU through the operational program of the European Regional Development Fund (ERDF) of the Valencian Community 2014–2020.

Peer reviewed