Distribution and Comprehensive Risk Evaluation of Cr, Cd, Fe, Zn, and Pb from Al Lith Coastal Seawater, Saudi Arabia
2024
Talal Alharbi | Abdelbaset S. El-Sorogy | Khaled Al-Kahtany
Seawater contamination is a global challenge due to its hazardous effects on marine organisms and human health. Twenty-three surface seawater samples were collected from the Al Lith intertidal area along the Saudi Red Sea coast to evaluate the ecological risks and document the potential sources of Cr, Cd, Fe, Zn, and Pb. Contamination factor (CF), contamination degree (Cd), water quality index (WQI), and heavy metal pollution index (HPI), as well as multivariate tools were applied. The average concentrations of HMs (μg/L) had the following order: Zn (6.616) > Pb (0.284) > Cd and Cr (0.268) > Fe (0.197). CF results showed moderate contamination of seawater with Cd and low contamination of Cr, Fe, Zn, and Pb. However, 26.09% of the samples showed considerable contamination with Cd. Average Cd values revealed low contamination with HMs, while 17.39% of the samples showed moderate contamination. HPI average values indicated medium pollution of Al Lith seawater, while 13 samples reported high pollution. The higher HPI values were reported in samples characterized by higher concentrations of HMs, particularly Cd and Zn. Correlation matrix and principal component analysis suggested anthropogenic sources for Pb and Zn, mostly from industrial and agricultural effluents, landfilling, and domestic wastewater, apart from their natural sources.
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