Possibility of novel hexose conjugation of a d-type trichothecene by trichodiene synthase gene-disrupted mutants of Fusarium species
2018
Matsui, K. (Toyo University, Kawagoe, Saitama (Japan). Graduate School of Science and Engineering) | Shinkai, K. | Adachi, K. | Takahashi-Ando, N.
Trichodermol, a non-Fusarium trichothecene, was fed to Tri5 gene-disrupted fusaria, which lack the gene encoding the enzyme for the first step of trichothecene biosynthesis. A tandem mass spectrum of the obtained product suggested that trichodermol was conjugated with hexose at position C-4 by deltaTri5 mutants of Fusarium sporotrichioides and F. graminearum.
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