The Synthesis of AgNPs/SAC Using Banana Frond Extract as a Bioreducing Agent and its Application as Photocatalyst in Methylene Blue Degradation
2024
Anti Kolonial Prodjosantoso, Tengku Khadijah Nurul Hanifah, Maximus Pranjoto Utomo, Cornelia Budimarwanti and Lis Permana Sari
Silver nanoparticles (AgNPs) were synthesized utilizing various methods, including bioreducing agents. The synthesis involved the use of silver nitrate (AgNO3) as the precursor and banana frond extract as the bioreducing agent, with different volume ratios being tested. Subsequently, the most optimal variant of AgNPs was immobilized onto activated carbon (AC) derived from soybean seeds. The AgNPs/SAC composite was subjected to thorough characterization using UV-Vis diffuse reflectance spectroscopy and X-ray diffraction (XRD). A series of degradation experiments were then conducted using methylene blue, with the reaction duration following a specific protocol. A comparison of methylene blue concentrations before and after the photodegradation process was made to assess the reaction’s efficacy. The findings revealed that the ideal ratio between the bioreducing agent and precursor was 9:30 (v/v). The AgNPs/SAC composite exhibited a peak absorption at a wavelength of 420-440 nm. The UV-DRS characterization of AgNPs/SAC unveiled a band gap energy of 1.52 eV. The AgNPs supported on AC displayed a peak absorption wavelength of 5,438.5 nm, showcasing a face-centered cubic (FCC) structure. The AgNPs/SAC effectively decreased the concentration of methylene blue through a combination of adsorption and photodegradation mechanisms, achieving efficiencies of 35.3813% and 81.1636%, respectively. The AgNPs/SAC composite demonstrates significant potential for efficient and sustainable water treatment.
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