Identification of Mattic Epipedon Degradation on the Northeastern Qinghai–Tibetan Plateau Using Hyperspectral Data

Accurate identification of mattic epipedon degradation is critically important for addressing ecological issues such as the weakening of alpine grassland carbon sink capacity and reduced soil and water conservation. However, efficient and rapid methods for its detection remain limited. This study aimed to clarify the hyperspectral response mechanisms of mattic epipedon degradation and, based on hyperspectral technology, to construct models for identifying degraded mattic epipedon and screen preprocessing methods suitable for different moisture conditions. The results showed the following: (1) The XGBoost model with preprocessing using multiplicative scatter correction combined with second derivative transformation (MSC+SD) performed best, achieving an identification accuracy and Kappa coefficient of 0.85 and 0.82, respectively. The characteristic bands were concentrated in the visible light range (446–450 nm) and short-wave infrared range (2134 nm, 2267–2269 nm), which are closely related to the spectral responses of organic carbon and mineral components. (2) Spectral reflectance was significantly negatively correlated with moisture content, and model accuracy decreased as moisture content increased. (3) After correction using the EPO algorithm, the model accuracy for the high-moisture group improved by 13.2–16.7%, whereas that for the low-moisture group (<15%) decreased by 7.5%, verifying 15% moisture content as the critical threshold for water interference. This study elucidated the impact mechanism of moisture on the hyperspectral characteristics of the mattic epipedon. The established MSC+SD-XGBoost model adapts to varying moisture conditions, providing technical support for the rapid monitoring of mattic epipedon degradation and holding significant practical value for carbon management in alpine ecosystems.