The Impact of pH on the Pore and Structural Characteristics of Acid-Modified Bentonites in Oxalate Solutions
2025
Maria Taxiarchou | Danai Tsakiri | Iliana Douni
The present study aims to create porous materials through the acid activation of bentonites using 0.5 M oxalic acid at different pH values. Two types of bentonites (containing aluminum montmorillonite and ferruginous montmorillonite) were treated with oxalate solutions at pH 1 to 5. During acid activation at the three pH values, Al, Fe, Mg and Si kinetics were monitored: the porosity of the samples was modified: and the specific surface area increased, while the crystal structure did not completely collapse. The optimum conditions occurred at pH 1, where the highest metal leaching was obtained for both samples. For the sample with aluminum smectite, the specific surface increased from 28.1 m2/g to 149 m2/g and the pore volume quadrupled. In the case of samples with ferruginous smectite, the specific surface area rose from 63. 2 m2/g to 372 m2/g and the pore volume increased sixfold. The mechanism of smectite activation was investigated, revealing that at the optimum experimental conditions, which is ferruginous bentonite activation at pH 1, the products have the highest concentration of small 30 to 50 Å: pores, which is attributed to the creation of an adequate number of active sites and the formation of aluminum complexes with the oxalate anions. The modified bentonites have elevated porosity: therefore, they could be used as adsorbents in industry.
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