Esterification of Glycerol and Rosin Catalyzed by Irganox 1425: A Kinetic Comparison to the Thermal Process
2025
Jorge García Montalvo | Natalia Robles-Anda | Felix García-Ochoa | M. Esther Gallardo | Miguel Ladero
Rosin is a biomass-based chemical raw material employed in multiple industries: paper, polymers, coatings, adhesives, and more, while glycerol production has experienced a notable increment in recent decades due to it being an unavoidable by-product of the biodiesel industry. Rosin polyol esters are of high interest, and a potential route for the valorization of glycerol. In this work, we compare in detail the esterification routes of rosin triglycerides via classical, industrial thermal processes at 260&ndash:280 °:C and similar processes catalyzed by Irganox 1425, a high-molecular-weight, multifunctional, phenolic, primary antioxidant produced by BASF and usually in rosin processes. Its chemical name is calcium bis(ethyl 3,5-di-tert-butyl-4-hydroxybenzylphosphonate). To this end, a novel RP-HPLC method provided us with a detailed description of the compositional evolution of the reacting media. These data have been the basis of a non-linear kinetic modeling procedure where we applied non-linear regression and numerical integration algorithms to determine the network of chemical reactions and the kinetic model of the rosin&ndash:glycerol esterification process. Furthermore, the comparison of such kinetic models and their parameters allows us to understand the kinetic effect of the addition of the homogeneous catalyst. The effect of Irganox 1425 results in a notable enhancement of the reaction rates, thus allowing for operation at lower temperatures and a reduction in side reactions as decarboxylation.
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