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Microbial Fuel Cell: Optimizing Graphene-Sponge Anode Thickness and Chamber pH Using Taguchi Experimental Method Full text
2024
Navarro, Emilio Steven C. | Boado, Melissa May M.
The rapid consumption of fossil fuels has led to calls to switch from non-renewable to renewable energy sources. Microbial fuel cells are a promising technology that simultaneously treats wastewater and produces power. This study used the Taguchi Experimental method to optimize anode thickness and pH to obtain the maximum power density of an air-cathode microbial fuel cell (ACMFC). The graphene-sponge (G-S) anode thickness and chamber pH were selected as operating parameters, with their corresponding levels. The L9 orthogonal array was chosen for the experimental design. According to the Taguchi Method, the optimum G-S anode thickness and chamber pH were determined to be 1.0 cm and 8.0, respectively. A confirmatory run was performed under these optimum conditions, and the maximum power density observed was 707.75 mW·m−3. Analysis of variance (ANOVA) was conducted to identify the percentage contributions of the operating parameters to the process, which were found to be 30.66% for pH and 69.34% for anode thickness.
Show more [+] Less [-]Heavy Metal Contamination of Surface Sediments-Soil Adjoining the Largest Copper Mine Waste Dump in Central India Using Multivariate Pattern Recognition Techniques and Geo-Statistical Mapping Full text
2024
Shukla, Anoop Kant | Pradhan, Manoj | Tiwari, Onkar Nath
This detailed study assessed heavy metal contamination of sediments/soil near central India’s largest copper mining area using 38 sampling sites within 10 km of the mine using atomic absorption spectroscopy. This study utilized multivariate pattern recognition methods, namely hierarchical clustering analysis (HCA) and principal component analysis (PCA), for source identification. Twelve parameters, i.e., copper (Cu), manganese (Mn), cobalt (Co), zinc (Zn), nickel (Ni), lead (Pb), organic matter (OM), cation exchange capacity (CEC), soil pH, distance (D), and elevation (E) were analyzed. The hierarchical cluster analysis (HCA) was used to analyze the sample sites with similar metal contamination and principal component analysis (PCA) was used to analyze the relationship between the parameters as well as to identify sources of heavy metal pollution. Three major pollution hotspots were detected by AHC and were classified as unpolluted/low pollution sites (UPS: mean concentration factor of 1.35 for Cu), highly polluted sites (HPS: mean concentration factor of 22 for Cu), and extremely polluted sites (EPS: mean concentration factor of 74 for Cu). PCA revealed three hidden factors/components, namely PC1 (explaining 38% of the variability), PC2 (18% of the variability), and PC3 (14% of the variability). Metals showed strong positive loading in PC1, explaining the highest variability. The mean content of Cu in soil/sediment samples was 502.526 mg/kg. The mean copper content was 10 times higher than the natural crustal value of 45mg/kg, indicating severe pollution in several sites around the study area. Mapping of copper contamination was conducted to reveal the spatial distribution of copper contamination using QGIS. This study exposes the heavy metal contamination level in surface sediments/soil and the effectiveness of pattern recognition techniques for the assessment of multivariate datasets in discerning spatial disparities and identifying the contamination causes.
Show more [+] Less [-]Survey and Characterization of Edible Fruit and Ethnomedicinal Trees in the Forest Landscape of Apayao Province Full text
2024
Martin, Hannie T. | Tomas, Olivia C. | Gabit, Ryan W. | Manicad, Maria Christina Z. | Rodolfo, David A.
This study was conducted in the six municipalities of Apayao Province, namely, Luna, Pudtol, Flora, Conner, Kabugao, and Calanasan. This aimed to survey and characterize the edible fruit and ethnomedicinal trees in the forest landscape of Apayao province. It determined the geographical location, morphological characteristics, ecological status, DNA sequencing, phytochemical contents, uses, and threats of the edible and ethnomedicinal trees in the forests of Apayao. The methods used were qualitative and quantitative research. Fifteen (15) edible and 10 ethnomedicinal trees were surveyed with sixteen (16) families were identified.Out of 25 edible and ethnomedicinal trees, the conservation status is endangered, threatened, rare, vulnerable, and least concerned. Out of 25 edible and ethnomedicinal fruit trees, most are with identity results that range from 93 to 100% identity. Flavonoids, tannins, and sapotin compounds are mostly present in edible and ethnomedicinal trees. The community members are using 15 different ethnomedicinal trees to address 32 health-related conditions. The results of the phytochemical analyses provide support evidence to support the traditional uses of ethnomedicinal trees. All surveyed trees are susceptible to pests, diseases, and destruction brought by natural phenomena such as the effect of climate change. A policy recommendation for the conservation and protection of edible and ethnomedicinal trees is then proposed.
Show more [+] Less [-]GIS-Based Mapping of the Water Quality and Geochemical Assessment of the Ionic Behavior in the Groundwater Aquifers of Middle Ganga Basin, Patna, India Full text
2024
Zafar, Mohammad Masroor | Sulaiman, Mohammed Aasif | Kumari, Anupma
The study implemented Geographic Information System (GIS) techniques and multivariate hydrogeochemical analysis to evaluate the spatial-temporal and seasonal variation in the groundwater quality of Patna, India. For this purpose, sixty groundwater samples were collected and analyzed for major anions and cations during the pre-monsoon, monsoon, and post-monsoon seasons of 2019-2020. The physicochemical parameters such as pH, EC (Electrical Conductivity), TDS (Total Dissolved Solids), TH (Total Hardness), Ca2+, Mg2+, Na+, K+, HCO3-, Cl-, SO42- were considered to evaluate the water quality index. The result revealed degradation in groundwater quality from pre-monsoon (49.21) to post-monsoon (74.48). EC, TDS, TH, Mg2+, Na+, Ca2+, K+, and HCO3- ions were found accountable for high WQI values at various sampling sites during different seasons. Spatial maps showed that 45 % of the sampling stations exhibited poor quality in all three seasons, where the eastern part of the studied region was revealed to be the most affected area. The application of multivariate statistical methods and hydrogeochemical investigation has clearly defined the dominant role of the weathering process, and reverse ion exchange mechanism in controlling the aquifer’s ionic chemistry. Moreover, poor seepage system, and waste leachate from the surface have been found as the main cause of high levels of Na+, K+, and Cl- in the eastern part of Patna.
Show more [+] Less [-]Stabilization of Dredged Soil by Compensating the Sand Content in the Jhelum River Full text
2024
Hamid, Yasir | Malik, Owais Shafi | Khan, Huma | Mehmood, Gauhar | Zakiah, Amina
River dredging is crucial for mitigating the risk of floods by enhancing the water-carrying capacity of rivers. Nevertheless, the key difficulty lies in the appropriate disposal of dredged material, resulting in escalated costs. Predominantly consisting of silt, the dredged material demonstrates constrained bearing capacity and strength. Nonetheless, there is a prospect to derive value from excavated sediments, with potential applications in diverse public works projects. The processed product derived from dredged material can serve diverse purposes, such as filling railway and highway embankments, as well as the subgrade of pavements. The comprehensive study involved analyzing the fundamental properties of the dredged material collected from the Allochibagh flood channel of the Jhelum River. The analysis focused on determining the basic geotechnical properties of the soil mass. The tests unveiled the fine and cohesive nature of the dredged soil. To enhance its properties, sand was introduced as a stabilizing agent in varying proportions. The investigation revealed an initial augmentation in compressive strength as the proportion of sand increased, attaining an optimal mixture whereafter the strength declined. This study explores the utilization of sand as a stabilizing agent for dredged soil to enhance its strength and optimize its application. The process of stabilizing dredged soil with sand demands a thorough examination of hydrogeological processes, the specific characteristics of the dredged soil, and the intricate transport of contaminants. This formal and multidisciplinary effort seeks to elevate the overall stability of the soil.
Show more [+] Less [-]Waste Generation and Recovery in a Developing Country: A Case Study of Western Province, Sri Lanka Full text
2024
Hemali, N. A. | De Alwis, A. A. P.
The study’s findings serve as a crucial foundation for policymakers, environmentalists, and stakeholders to take necessary actions and develop sustainable waste management strategies tailored to the specific challenges faced in the Western Province of Sri Lanka, contributing to broader global efforts to mitigate the growing waste crisis. It’s a significant concern that the volume of waste is expected to triple by 2050, and the current waste management practices seem insufficient to handle this growth sustainably. The study indicates a per capita waste generation of 0.43 kg in Sri Lanka, with the Western Province at a higher rate of 0.53 kg. This data points to the urgency of addressing waste management practices in this region, especially considering its significance in the country’s GDP. The results also show that the total municipal waste generation in the Western Province is 3248 kg per day whereas the recovery is only 25% (803 kg) in terms of recycling and composting. Burning, burying, and open dumping are highlighted as other prevailing practices for managing waste, which have adverse impacts on the environment and public health. Further research is recommended to identify and address these unaccounted waste streams, especially those at the household level.
Show more [+] Less [-]Potential Use of Portulaca Plant Species in Removing Estradiol Hormone Pollutants in the Surface Water of Bengawan Solo River Full text
2024
Khoiriyah, Siti | ., Suranto | Setyono, Prabang | Gravitiani, Evi | Hidayat, Agung
Bengawan Solo River water is a source of drinking water and raw materials for the government of Surakarta city, but the water has been mixed with domestic, industrial, and agricultural wastes. The waste contains estradiol-17 derived from urine and feces, both from livestock and humans as well as industries around the sub-watershed Bengawan Solo River. The content of estradiol-17 in the Bengawan Solo sub-watershed is quite high. This study is the first conducted in Bengawan Solo River to look at natural estrogens that are very rarely studied in the environment, which are likely could cause several health effects in humans and wildlife due to their relatively strong estrogenic potential and high levels in wastewater and river water. Therefore, research on the elimination of these compounds using effective, energy-efficient, and low-maintenance technologies for water treatment such as phytoremediation is highly expected. The purposes of this study were to identify estradiol, to measure the estradiol levels through HPLC tests as well as to test the effectiveness of phytoremediation with Portulaca plant as biological agents. The results show that the water of Bengawan Solo River contained estradiol substances ranging from 3.88 ppm to 5.76 ppm. The Portulaca plant species was effective at eliminating estrogenic waste up to 99.89%.
Show more [+] Less [-]Effects of Rainfall Intensity, Kinetic Energy and Slope Angle to the Upslope, Downslope, and Lateral Slope Components of Splash Erosion in Hillslope Agriculture: A Case in Badiangan, Ajuy, Iloilo Full text
2024
Cruz, Shevanee Ruth G. Dela | Fornis, Ricardo L.
This study was conducted in Barangay Badiangan, Ajuy, Iloilo City, Philippines (11°10’N, 122°58’E) to determine the effects of rainfall intensity and other rainfall-derived parameters on the directional components of splash erosion in hillslopes. There are five experimental set-ups with slope angles ranging from 0% to 48% were tested under natural rainfall conditions using a modified splash collector. The data collected shows that kinetic energy, slope, and rainfall intensity have shown significant effects on splash erosion. The models obtained using regression analysis are 𝑄𝑄𝑑𝑑𝑑𝑑𝑑𝑑=0.0093(𝐾𝐾𝐾𝐾0.80) and 𝑄𝑄𝑡 𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡=0.060(𝐾𝐾𝐾𝐾0.107)(𝑆𝑆0.700)(𝐼𝐼200.700) . The model equation performance has been validated using the Standard Error of Estimates with values of 12 and 9.4 for splash detachment and splash transport, respectively. The constants used for kinetic energy in detachment and slope in transport align with the research by Quansah (1981) for sandy soil, which is similar (the characteristics) to the soil at our research site. Additionally, rainfall intensity, especially with a 20-min duration, generated the best model as it yielded the lowest SEE value for all cases.
Show more [+] Less [-]Research Insights into Punjab’s Stubble Burning Menace Full text
2024
Kohli, Ruchi | Mittal, Anu | Mittal, Amit
The current investigation endeavors to evaluate the prevalence of stubble burning in India, with a special focus on the state of Punjab. The study emphasizes the enormity of stubble burning by examining farm fire incidents, pollutant emissions, its detrimental impacts. It supports the effective management of crop residue along with proposing alternatives to stubble burning. The article conveys the message that stubble burning can result in deleterious effects on the environment, human health, crop growth, natural ecosystems, visibility, and physical infrastructure. The key solutions lie in education, functional literacy, a heightened awareness of environmental laws, rights and duties, stringent governance, and socially responsible public, promoting adherence to the National Green Tribunal’s guidelines for managing crop residue and enlightening farmers about the ill effects of stubble burning on animal, soil, human health, crop biodiversity, and climate change. The available data of districts of Punjab indicates the recent waning trend in stubble burning, thus heralding a positive indication of environmental preservation. Decreased stubble burning is the reward of untiring government initiatives, support and subsidies, awareness programs, advanced research and technology, and enforcement of stringent regulations combined with recognition of the deleterious environmental impacts of stubble burning. This research article indicates that there is still a need for efforts to be made to eliminate stubble burning altogether.
Show more [+] Less [-]Water Treatment: Evaluation of Maleic Acid-Acrylamide Copolymer Inhibitor Efficiency on Calcite Scale by Response Surface Methodology Full text
2024
Senthilmurugan, Balasubramanian | Radhakrishnan, Jayaprakash Sandhala
Mineral scales of calcite are common in the oil field and pose a serious integrity problem in the wellbore, flow lines, and equipment. It is also a challenge faced by industries such as refineries and power plants. Scale deposition is a complex process depending on various factors such as concentration of scaling species, temperature, pH, and flow rates. Deterministic models are used to predict the scale formation from the level of supersaturation of the scaling species in the water at the operating conditions. However, due to the complexity of the interaction of variables affecting the scaling and inhibition by chemicals, it is suitable to be represented by statistical models. This work focused on applying statistical analysis techniques such as response surface methodology to understand the effect of different operating parameters on the inhibition efficiency of maleic acid-acrylamide copolymer on CaCO3 scales. The copolymer was synthesized, and its inhibition efficiency on the calcite scale was tested using static jar tests at different pH, temperature, and inhibitor concentrations. The effect of the critical parameters on the inhibition efficiency was analyzed using the statistical technique of Response Surface Methodology (RSM). The design of experiments (DoE) was created using a Box–Behnken design with three levels for each factor. The linear and the quadratic effects of the factors were studied and the interaction effects were analyzed using analyses of variance (ANOVA) and RSM. A desirability function was used to optimize the performance for the combination of the variables. The analysis showed that the linear effect of the parameters had the highest impact on the inhibition efficiency. Significant interaction effects were also identified between the operating variables. A transfer function was used to model the experimental data of inhibitor performance.
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