The present study aims at determining the geotechnical properties of the tailings and the natural bed at Iran Mineral Processing Company, Sites 1 and 5. It qualitatively studies the subsurface layers of the company’s tailings storage site. After drilling different boreholes and conducting in-situ tests, it has made laboratory analyses in the form of field exploration to determine the geotechnical parameters of the extracted samples. Results from the analyses show the permeability coefficient of the subsurface layer of Site No. 1 and 5 to be very small, in the range of 10-7 cm/sec. Considering the conformity of permeability coefficient, percentage of fine grains (98% to 99%), plasticity index (28.5-29.5), and clay content of different layers of Sites 1 and 5 (68%-80%), based on the compacted clay liner criteria, it can be concluded that by nature, the subsurface layers of the mentioned sites are sealed with no need for any compacted clay liner. The tailings for storage Site 5 are fine-grained (80-88<75mm), basically in ML range according to USCS system, with a permeability coefficient of about 10-6 cm/sec. Therefore, the tailings themselves act as a relatively primary sealing layer against the infiltration of hazardous leachates into the natural bed. The method, used in the process of site selection of tailings storage facilities (TSF), can cut the construction time as well as the expenditures, thus reducing the production costs in the long run.

High levels of dioxins and dioxin-like compounds in the food and their adverse effects on human health are of increasing concern. Since milk is one of the most essential human nutritional resources, the present study aims at determining dioxins and PCBs in raw milk samples from four farms in North of Iran and raw and pasteurized samples from three farms and five dairy factories in Vicinity of Tehran (capital of Iran). Total toxic equivalence (TEQ) of dioxin and PCBs have been determined, using the DR-CALUX® bioassay. Results reveal that all samples are contaminated with dioxins and PCBs, comparatively. The total dioxins and PCBs levels in raw milk samples from the north range from 4.08 to 0.97 pg/gfat and for the raw samples and pasteurized samples from Tehran Province from 1.89 to 0.63 pg/gfat and 0.1 to 0.03 pg/gfat, respectively. The mean concentration of dioxins/PCBs is higher in samples from the north of Iran. This may be because of the common method of removing domestic and agricultural disposal in this area.

Plastic production has inevitably increased in the past few decades and is one of the diverse material used in today’s world. With this increasing production and wider use, the aquatic ecosystems have become the trash barrel for all kinds of plastic resulting in it becoming a looming spectre to the habitat and functions of both inland and offshore ecosystems. Plastic pollution is considered as an emerging global environmental concern which could significantly affect the biological diversity and may have potential to cause inimical effects on human health. These plastics have shown to gradually degrade into micro fragments and are reported to cause toxic effects on the aquatic organisms. In comparison to the studies on presence of microplastic in marine ecosystems, the studies on the presence of it in freshwater ecosystems have received relatively lesser attention although some studies have shown that the contamination is as grievous as that of in marine environment. This review article focuses on the literature available on the reports of microplastic occurrence, its distribution in freshwater ecosystems across the world and its insidious effects which are of emerging concern. The effect of such microplastic ingestion in both aquatic organisms and the potential health hazards due to such plastic consumption in humans have also been examined. The paper also discusses the existing knowledge gaps so that future research directions can be taken accordingly and the findings in this paper would significantly help all the countries across the world to understand the present plastic pollution scenario and work towards the mitigation of the same.

In order to ensure radiation monitoring and protection, investigation and assessment of radiological risks that may be associated with the consumption of packaged table waters commonly consumed in Ogbomoso and Ilorin metropolis, Nigeria, was carried out. The measurements were carried out using a ‘3 x 3’ inch lead-shielded NaI (Tl) detector coupled through coaxial cable to a multichannel analyser. The measured activity concentrations of the natural radionuclides in the packaged drinking water sample are mostly within the recommended limits. The estimated mean Annual Effective Dose was found to be within the acceptable limits of 1 mSv/y for the general populace except for the infants which is slightly higher for some of the samples. The estimated Excess Lifetime Cancer Risk were found to be lower than the world average value of 0.2 x 10-3 in only two of the selected packaged drinking water. This implies the possibility of developing cancer over a lifetime considering seventy years as the average life span is considerably high.

The ability of fungi to act as bio-sorbent had been extensively evaluated and has shown excellent metal sequestering ability for heavy metals such as cadmium, copper, zinc, lead, iron, nickel, radium, thorium, and uranium from aqueous solution. In the present study, tolerance, removal efficiency and adsorption capacity of hexavalent chromium using isolated fungal strains were analysed. Total nine fungal isolates were obtained from organic pollutants and metals contaminated Gujarat Industrial Development Cooperation sites. Filamentous fungi isolated belonged to Aspergillus spp., Rhizopus spp., Trichoderma spp., and Penicillium spp. Chromium sorption experiments using isolated fungal strains were carried out to check adsorption capacity and adsorption intensity. At higher chromium concentration, removal efficiency and adsorption capacity were observed in the order of Aspergills candidus > Aspergillus ochraceus > Aspergillus flavus > Rhizopus spp. > Trichoderma spp. A. candidus showed higher adsorption capacity, 5.49mg/g with 98.75% chromium removal efficiency at 150ppm of hexavalent chromium. The observed RL value for Langmuir isotherm for all the three concentrations was less than 1, depicting favourable sorption and in Freundlich isotherm, the value of 1/n exceeds more than 1 showing co-operative or similar type of adsorption.

Atmospheric aerosols are very crucial from air pollution and health perspective as well as for regional and global climate. This paper attempts to summarize the aerosol loading and their properties such as Aerosol Optical Depth (AOD), Single Scattering Albedo (SSA), Angstrom exponent, and Radiative forcing, over India. All the above mentioned parameters have shown significant variability with change in the site and season. From various studies it was observed that AOD is relatively higher over Northern part of India as compared to Southern and Eastern part. Generally, lower values of SSA were observed over all sites during winter and post-monsoon seasons which indicates the dominance of absorbing type aerosol during these seasons. Also the ARF within atmosphere showed comparatively higher values during November-December and lower value during August and September all over the India. The current state of knowledge about aerosol sources, interactions and their effects on environment is limited because of its complexity. Therefore, more focused research in needed to understand the aerosol’s role in climatic phenomenon.

A large anthropogenic source of mercury pollution is mercury-dependent artisanal and small-scale gold mining (ASGM). Thabeikkyin Township is a small-scale gold mining township located in Pyin Oo Lwin District in the Mandalay Region, Myanmar. The villages of Thabeikkyin Township engage in gold ore crushing, screening, refining, and other mining activities for a living. Miners in this area commonly use mercury for gold recovery by heating amalgam at their homes, gold shops, on the street, and near the riverbank. The evaporated mercury is released into the atmosphere during the heating process and then transported and deposited in the surrounding environments, resulting in the mercury pollution of air, water, soil, etc. To assess atmospheric mercury pollution, a preliminary study on the environmental mercury contamination from ASGM was conducted in Thabeikkyin Township. High mercury concentrations were observed in plant samples collected near the refining sites, ranging 0.33–6.51 ug/g, compared with 0.02 ug/g in Wet Thay Village, where no mercury use was reported. Correlation coefficients between Hg and other heavy metals showed that no heavy metal concentration significantly correlated with that of Hg. The results indicated that the atmospheric environment in the ASGM area of Thabeikkyin Township was contaminated with mercury originating from ASGM, which could very likely deteriorate the health of surrounding residents.

The increased consumption of fossil fuels provokes high levels of carbon dioxide (CO2) emissions, which give rise to serious environmental issues. Accordingly, designing and utilizing new classes of materials, such as Schiff bases, to capture CO2 gained significant attention from researchers worldwide. In the present work, two Schiff bases were synthesized and examined as storage materials for carbon dioxide gas. The prepared compounds were obtained by reacting trimethoprim with two aldehydes severally (benzaldehyde and parabromobenzaldehyde) in boiling methanol. The surface morphology of the compounds was investigated via field emission scanning electron microscopy (FESEM). The Brunauer-Emmett-Teller (BET) test showed that Schiff bases 1 and 2 have surface areas of 17.993 and 2.732 m2/g, pore volumes of 0.008 and 0.005 cm3/g, and pore diameters of 17.02 and 74.89 nm, respectively. Reasonable uptake values of CO2 (31.36 cm3/g, 6.2 wt%) and (25.30 cm3/g, 5.0 wt%) were achieved by the prepared Schiff bases 1 and 2, respectively, at 313 K temperature and 40 bars pressure.

Saraca asoca bark has long been used in traditional Indian medicine. Considering its low cost and non-toxic nature, it can find application as a biosorbent. This article explores the application of Saraca asoca bark powder (SABP) for biosorption of hexavalent chromium. Various analytical techniques including Field emission scanning electron microscope (FESEM) attached with energy dispersive spectrometer (EDS), Fourier transform infrared spectroscopy (FTIR) and point of zero charge (pHpzc) were adopted in order to identify the physico-chemical features of SABP. Factors such as pH (2-8), contact time (for 3 hours), initial Cr (VI) concentration (10 – 250 mg/l) and temperature (15 - 35°C) were examined for their influence on Cr (VI) biosorption via batch studies. Biosorption data clearly followed Redlich-Peterson isotherm model as compared to Langmuir and Freundlich models. The Langmuir monolayer adsorption capacities (Qm) at 15, 25 and 35°C were 123.4, 125.0 and 175.4 mg/g respectively. Biosorption followed pseudo-second-order kinetics and the mechanism of diffusion was governed by both surface sorption and pore diffusion as demonstrated by the plot for Intraparticle diffusion model and the pore diffusion coefficient (Dp~10-9 cm2/s). The nature of biosorption was found to be spontaneous and endothermic as reflected through various thermodynamic parameters such as the free energy change (ΔG = -3.0 to -3.7 kJ/mol), entropy change (ΔS = 37.8 J/K/mol) and enthalpy change (ΔH = 7.9 kJ/mol). The study recommends that SABP may be utilized as a potential biosorbent for Cr(VI) ions.

In this work, Fe3O4-SiO2 nanoparticles were synthesized, characterized, and applied as adsorbent material to remove methyl blue stain from an aqueous solution. The prepared nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), and Brunauer–Emmett–Teller (BET) to determine the physical surface properties and correlate them to the adsorption efficiency. In addition, this study investigated the influence of several parameters on the removal percentage and adsorption capacity. Specifically, this study investigated the impact of changing the following parameters: pH (1 – 8), agitation speed (Uspeed; 100 - 350 rpm), initial methyl blue (MB) concentration (1 - 100 mg/L), adsorbent dose (0.05 to 0.15 g), and contact time (10 - 100 min). The characterization study reveals that the prepared material has an excellent surface area (385 ± 5 m2/g) and pore volume (0.31 cm3/g) which enhances the adsorption capacity. In addition, the prepared material showed excellent efficiency where the removal percentage reached 99.0±1% at the optimal operating conditions and the maximum adsorption capacity was 40 mg/g. This study delivers a full elucidation of the adsorption of MB dye by Fe3O4-SiO2 NPs which considers a promising inexpensive adsorbent. It also delivers important insight information about the adsorption process and the influence of each parameter, which fill the lack in this field.