This study was conducted in Barangay Badiangan, Ajuy, Iloilo City, Philippines (11°10’N, 122°58’E) to determine the effects of rainfall intensity and other rainfall-derived parameters on the directional components of splash erosion in hillslopes. There are five experimental set-ups with slope angles ranging from 0% to 48% were tested under natural rainfall conditions using a modified splash collector. The data collected shows that kinetic energy, slope, and rainfall intensity have shown significant effects on splash erosion. The models obtained using regression analysis are 𝑄𝑄𝑑𝑑𝑑𝑑𝑑𝑑=0.0093(𝐾𝐾𝐾𝐾0.80) and 𝑄𝑄𝑡 𝑡𝑡𝑡𝑡𝑡𝑡𝑡𝑡=0.060(𝐾𝐾𝐾𝐾0.107)(𝑆𝑆0.700)(𝐼𝐼200.700) . The model equation performance has been validated using the Standard Error of Estimates with values of 12 and 9.4 for splash detachment and splash transport, respectively. The constants used for kinetic energy in detachment and slope in transport align with the research by Quansah (1981) for sandy soil, which is similar (the characteristics) to the soil at our research site. Additionally, rainfall intensity, especially with a 20-min duration, generated the best model as it yielded the lowest SEE value for all cases.

Locally available apricot seed shell as agro-waste was used for the preparation of adsorbents. The biochar was prepared at 370°C via pyrolysis and 80 mesh particle sizes were modified by 1N HCl. Nitrate adsorption and effect of co-ions from aqueous solution were studied under batch model using apricot seed shell powder (ASSP), apricot seed shell biochar (ASSB), and activated apricot seed shell biochar (AASSB). FTIR and pHPZC measurements were used to characterize the adsorbents. Based on the experimental findings, the optimum conditions follow pH 2, 0.3g dosage, initial concentration of 50 mg.L-1, and contact time of 90 min. The three forms of adsorbent exhibited good adsorption for nitrate. However, the maximum percentage removal of nitrate ions from the aqueous solution followed the order AASSB>ASSB>ASSP. The adsorption kinetic of nitrate ion was best fitted by pseudo 2nd order, and the parameters of adsorption isotherms elucidated favorable and improved sorption. This agro-waste could be used to develop sustainable adsorbents in water and wastewater treatment methods and has great potential to replace commercially available sorbents.

This research delves into the promising domain of CO2 capture through fine solid activated carbon adsorbent, offering a more energy-efficient alternative to traditional adsorption methods. The central challenge addressed here is the utility of cheaper CO2 adsorbent, fine powder materials whose properties can be precisely tailored via molecular-level fictionalization. Equally vital is selecting an optimal fluidizing column configuration that maximizes CO2 interaction with adsorption particles and enhances adsorption efficiency. The proposed solution is a fluidized bed column uniquely equipped with integrated acoustic vibrations to counteract interparticle forces common in fine powders. For adsorption evaluations, sound-assisted fluidized-bed experimentation on a laboratory size was set up. Adsorbent material activated carbon made up of coal underwent rigorous testing between a range of 20 Hz-200 Hz and 20 dB-135 dB. Results reveal the beneficial effects of acoustic enhancement of fluidization quality and adsorption efficiency, increased adsorption capacity, enhanced bed utilization, and accelerated adsorption rates. Extensive research has been conducted on the detailed effects of major operational variables on adsorption performance, notably frequency, sound intensity, and minimum fluidization velocity. The findings highlight the pivotal role of particle size with mean size 75 microns range as a determinant of adsorption capacity at 100 Hz and 125 dB. At the end of experimentation, the adsorbent considered for the experiment is compared to the study adsorption capacity at operating conditions. The research concludes with a discussion on the effects of influencing parameters for adsorption on employing sound vibrations using fluidization technique adsorption for CO2 capture.

The inhibitory effect of Rosemary oil on the corrosion of aluminum alloy EN AW-2011 in 1M H2SO4 solution was studied by weight loss and electrochemical methods such as open circuit potential (OCP), linear sweep voltammetry (LSV) and linear polarization resistance (LPR). The inhibition efficiency increases with increasing the concentration and shows maximum inhibition efficiency (70.7 %) at optimum concentration (0.05 g.L-1). The linear polarization resistance measurements show that the presence of Rosemary oil in 1M H2SO4 solution influences polarization resistance increasing and corrosion current decreasing. The voltammetric curve shows that Rosemary oil reduces the anodic process. Open circuit potential results confirmed that organic compounds present in Rosemary oil can form a protective layer on aluminum surfaces. The inhibitive effect was probably caused by the adsorption of organic compounds such as 1,8-cineole, α-pinene, borneol, limonene, and myrcene on aluminum surfaces which are non-toxic and environmentally friendly. This study showed that the essential oil of Rosemary could be used as an environmentally friendly inhibitor of the corrosion of alloy EN AW-2011 in an acidic medium.

Due to enormous quantities with hazards and complexity in nature is a big challenge for effective treatment of wastewater from pharmaceutical processes including herbal extraction through conventional methods of distillation. The situation is further aggravated in countries facing high rising population, urbanization, and industrialization resulting in the generation of industrial wastes. The study has been carried out in the herbal extraction industry by conducting stage-wise sampling of ETP based on the conventional method and further coupled with ozonation as an advanced treatment to comply with regulatory standards. Additionally, the same process was studied that implementing the best available technology (BAT) by providing ETP with advanced technology modules such as MBR (membrane bioreactor) + RO + O3 has not only resulted in compliance with standards but also reuse of treated wastewater into the process and utilities has been proved to be techno-economically a viable and sustainable option. Modifying existing aeration tanks and advanced oxidation through ozone injection post-biological treatment has resulted in COD and BOD reduction of 96.42% and 99.0% respectively. Whereas in the case of MBR + RO + O3, the values of pH, BOD, COD, TSS, and sulfide have been observed as 8.32, 2.0 mg.L-1, 14.0 mg.L-1, 1.0 mg.L-1 and 0.0 mg.L-1 respectively and 98% recovery of treated effluent, thus saving 44 KL.day-1 of freshwater resulting into significant financial benefits of Rupees 12.59 acs annually, which otherwise was outsourced through tankers.

Marginal land has low nutrient content (nitrogen, phosphorus, potassium). Addressing nutrient deficiencies on marginal land requires a strategic approach. Biological fertilizers like Arbuscular Mycorrhizal Fungi (AMF) and plant growth-promoting rhizobacteria (PGPR) enhance nutrient availability through symbiotic interactions. In addition, organic fertilizers such as compost could provide organic matter and improve soil structure to increase plant growth and productivity. Combining these three fertilizers with the addition of low doses of NPK fertilizer can increase the growth and productivity of maize crops on sub-marginal land. This study aims to determine the effect of AMF, consortium of PGPR, and a low dose of NPK on the growth and productivity of maize and soil nutrients on sub-marginal land by measuring plant growth up to 8 WAP (week after planting) (parameters: plant height, stem diameter, number of leaves, leaf area, chlorophyll content, stomatal density) and productivity (parameters: cob length, cob weight with husk, fresh weight, dry weight) and levels of N, P, and K elements at 8 WAP in the soil after planting. All treatments showed an increase in the level of N and K elements, while the P element showed a decrease compared to the control (soil without treatment). Moreover, each parameter did not show a significant difference, but the P2 (Compost + PGPR consortium + AMF + 50% of NPK) treatment showed the best growth and productivity. Overall, the data showed the utilization of PGPR and AMF combination was able to reduce the usage of chemical fertilizer by 50%.

Phytoremediation is one of the non-energy consuming processes of remediating polluted water. However, the disposal of post-remediated plants poses a threat of the re-introduction of pollutants back into the ecosystem. Re-routing remediated pollutants for commercial application could be one way to reduce the re-introduction of pollutants in an ecosystem. Heavy metal pollution in water bodies is one issue, which can be mitigated to an extent with phytoremediation. In the current study, the effect of heavy metal phytoremediation on the phytochemical fingerprint and bioactivity of Pistia stratiotes L. was investigated. Pistia stratiotes L. was subjected to different concentrations of iron (Fe) and lead (Pb), in the range of 5-20 ppm. Different parameters such as heavy metal estimation (in plants and water post-treatment), thin layer chromatography (TLC), antioxidant activity, and antiurolithic activity were measured. Post remediation, heavy metal concentration was found to be comparatively higher in roots (16.515 ± 0.008 mg.g-1 and 5.25 ± 0.086 mg.g-1 when treated with 15 ppm iron and lead respectively). TLC revealed differences between the fingerprints of treated and untreated plants. Some bands increased in intensity as the concentration of heavy metal increased, while some bands which were present in untreated, were absent in treated plant samples. Antioxidant activity of treated plants shows lesser IC50 values, compared to untreated, in that, treated leaves show better activity (IC50 = 1.8 ± 0.5220 mg.mL-1 of leaf treated with 2 ppm iron as opposed to IC50 > 5 mg.mL-1 of untreated leaf extract). The treated plants revealed good antiurolithic activity compared to untreated, in that, the percentage inhibition showed by Iron treated leaves and roots was better (96.87% and 98.95% exhibited by iron-10 ppm treated leaves and roots respectively), while the untreated showed a maximum of only 68.75% inhibition. The results suggest that the bioactivity of the plant extracts increases post-remediation. Potential applications of these extracts can be explored such as nanoparticle synthesis, drug discovery, etc.

Naturally derived cyanotoxins, cylindrospermopsin (CYN), and microcystin-LR (MC-LR) have shown hepatotoxic and nephrotoxic effects in several studies. The present study aimed to determine the possible nephrotoxicity of MC-LR and CYN on mammalian kidneys using male Wistar rats as an animal model. Potential nephrotoxicity was evaluated at different doses of CYN (0.175 μg.kg-1, 0.140 μg.kg-1, 0.105 μg.kg-1) and MC-LR (0.105 μg.kg-1, 0.070 μg.kg-1, 0.035 μg.kg-1) was observed. Water samples from dug wells contaminated with CYN (0.161 μg.kg-1) and MC-LR (0.091 μg.kg-1) from the Padaviya area in Anuradhapura, Sri Lanka were used as environmental samples. The control groups were treated with distilled water. The exposure time of rats to the toxin was 90 days. Evaluation of urinary creatinine, serum creatinine, and Kidney Injury Molecule-1 (KIM-1) were estimated using standard protocols. A significant increase in serum creatinine levels was observed in all CYN and MC-LR treated groups (p<0.05) after 7 and 42 days of exposure, respectively, compared to control. It was found a decrease of urine creatinine when rats were treated with different concentrations of CYN and MC-LR (p<0.05) after 7 days compared to the control. The highest KIM-1 concentrations were recorded at 0.175 μg.kg-1 of CYN and 0.105 μg.kg-1 of MC-LR. The concentrations of KIM-1 in the control groups for CYN-treated and MC-LR-treated were not detected. Luminal protein, nuclear pyknosis, mild tubular epithelial swelling, vascular congestion, and interstitial inflammation in CYN and MC-LR treated groups were common. No predominant changes were observed in the control groups treated with CYN and MC-LR. The results of the present study confirm that the consumption of CYN and MC-LR-contaminated water may lead to kidney injury in Wistar rats.

Composting is an integral component of sustainable Municipal Solid Waste (MSW) management within the circular bio-economy platform. However, it faces challenges due to malodorous emissions that impact environmental and societal equilibrium. The present study aims to minimize odorous emissions and expedite compost maturation using a novel, efficient microbial consortium. Bacteria sourced from open dump sites in Sri Lanka were carefully screened based on concurrent enzyme production. Five developed consortia were tested for their performance in reducing malodors during the composting process of MSW. Consortium No. 5 (C5), comprised of Bacillus haynesii, Bacillus amyloliquefaciens, and Bacillus safensis, demonstrated outstanding performance with a significant (p < 0.05) reduction in odorous emissions. Additionally, consortium C5 exhibited impressive control over gas emissions, maintaining VOC, CH4, NH3, and H2S concentrations within ranges of 0.5-6 ppm, 0.5-0.8 ppm, 0.3-0.5 ppm, and 0.5-0.6 ppm, respectively, compared to control concentrations of 4.5-10.2 ppm, 0.5-5.5 ppm, 0.3-5.5 ppm, and 0.5-6.4 ppm, respectively. Additionally, comprehensive Electronic nose (E-nose) analysis substantiated C5’s efficiency in attenuating Methane-Aliphatic compounds, Sulfur and Aromatic compounds, along with low-polarity aromatic and alkane compounds, all with statistical significance (p < 0.05). Further, the developed consortium could reduce the composting time from 110 ± 10 days to 17 ± 3 days, offering a sustainable solution for global MSW management.

This study presents a comprehensive investigation into the production of amylase, a crucial enzyme with wide-ranging industrial applications, using locally sourced substrates from Kachchh, Gujarat. The research employed the Bacillus licheniformis strain and substrates such as coconut, rice husk, wheat bran, paddy straw, and maize straw. The study found paddy straw to be the most promising substrate for amylase production. The research also systematically optimized various process parameters for amylase production in Solid-State Fermentation (SSF) using the One Variable at a Time (OVAT) method. These parameters included incubation period, temperature, inoculum level, additional carbon sources, starch concentrations, additional nitrogen sources, initial pH, different mineral salt ions, initial moisture level, and surfactants. The results showed that the optimal conditions for maximum amylase yield were an incubation period of 48 hours, an incubation temperature of 35°C, an inoculum level of 10%, starch as the additional carbon source, a starch concentration of 2.5%, yeast extract as the additional nitrogen source, an initial pH of 7, NaCl as the mineral salt, an initial moisture level of 75%, and Tween 80 as the surfactant. This research provides a reliable and sustainable approach to enzyme production, offering valuable insights for the optimization of the solid-state fermentation process for maximum amylase production.