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The influence of soil acidification on N2O emissions derived from fungal and bacterial denitrification using dual isotopocule mapping and acetylene inhibition
2022
Zheng, Qian | Ding, Junjun | Lin, Wei | Yao, Zhipeng | Li, Qiaozhen | Xu, Chunying | Zhuang, Shan | Kou, Xinyue | Li, Yuzhong
Denitrification, as both origins and sinks of N₂O, occurs extensively, and is of critical importance for regulating N₂O emissions in acidified soils. However, whether soil acidification stimulates N₂O emissions, and if so for what reason contributes to stimulate the emissions is uncertain and how the N₂O fractions from fungal (ffD) and bacterial (fbD) denitrification change with soil pH is unclear. Thus, a pH gradient (6.2, 7.1, 8.7) was set via manipulating cropland soils (initial pH 8.7) in North China to illustrate the effect of soil acidification on fungal and bacterial denitrification after the addition of KNO₃ and glucose. For source partitioning, we used and compared SP/δ¹⁸O mapping approach (SP/δ¹⁸O MAP) and acetylene inhibition technique combined isotope two endmember mixing model (AIT-IEM). The results showed significantly higher N₂O emissions in the acidified soils (pH 6.2 and pH 7.1) compared with the initial soil (pH 8.7). The cumulative N₂O emissions during the whole incubation period (15 days) ranged from 7.1 mg N kg⁻¹ for pH 8.7–18.9 mg N kg⁻¹ for pH 6.2. With the addition of glucose, relative to treatments without glucose, this emission also increased with the decrement of pH values, and were significantly stimulated. Similarly, the highest N₂O emissions and N₂O/(N₂O + N₂) ratios (rN₂O) were observed in the pH 6.2 treatment. But the difference was the highest cumulative N₂O + N₂ emissions, which were recorded in the pH 7.1 treatment based on SP/δ¹⁸O MAP. Based on both approaches, ffD values slightly increased with the acidification of soil, and bacterial denitrification was the dominant pathway in all treatments. The SP/δ¹⁸O MAP data indicated that both the rN₂O and ffD were lower compared to AIT-IEM. It has been known for long that low pH may lead to high rN₂O of denitrification and ffD, but our documentation of a pervasive pH-control of rN₂O and ffD by utilizing combined SP/δ¹⁸O MAP and AIT-IEM is new. The results of the evaluated N₂O emissions by acidified soils are finely explained by high rN₂O and enhanced ffD. We argue that soil pH management should be high on the agenda for mitigating N₂O emissions in the future, particularly for regions where long-term excessive nitrogen fertilizer is likely to acidify the soils.
Show more [+] Less [-]Impacts of oxalic acid-activated phosphate rock and root-induced changes on Pb bioavailability in the rhizosphere and its distribution in mung bean plant
2021
Rasool, Bilal | ur-Rahman, Mahmood | Adnan Ramzani, Pia Muhammad | Zubair, Muhammad | Khan, Muhammad Asaf | Lewińska, Karolina | Turan, Veysel | Karczewska, Anna | Khan, Shahbaz Ali | Farhad, Muniba | Tauqeer, Hafiz Muhammad | Iqbal, Muhammad
Rhizosphere acidification in leguminous plants can release P from the dissolution of phosphate compounds which can reduce Pb bioavailability to them via the formation of insoluble Pb compounds in their rhizosphere. A soil polluted from Pb-acid batteries effluent (SPBE), having total Pb = 639 mg kg⁻¹, was amended with six different rates (0, 0.5, 1, 2, 4 and 6%) of oxalic acid-activated phosphate rock (OAPR) and their effects on pH, available P and bioavailable Pb concentrations in the rhizosphere and bulk soils of mung bean plant were evaluated. Furthermore, the effects of these variant OAPR rates on Pb concentrations in plant parts, bioaccumulation factor (BAF) and translocation factor (TF) for Pb in grain and traits like productivity, the activities of antioxidant enzymes, and grain biochemistry were investigated. Results revealed that increasing rates of OAPR significantly increased pH values and available P while decreased bioavailable Pb concentrations in the rhizosphere over control. The highest dissolution of P in the rhizosphere was with 4 and 6% OAPR rates. As a result, the formation of insoluble Pb compounds affected on reduced Pb concentrations in shoots, roots, and grain in addition to lower grain BAF and TF values for Pb over control. Likewise, the highest plant productivity, improved grain biochemistry, high Ca and Mg concentrations, least oxidative stress, and enhanced soil alkaline phosphatase activity were found with 4 and 6% OAPR rates. The OAPR 4% rate is suggested for reducing grain Pb concentration, cell oxidative injury, and improving grain biochemistry in mung bean.
Show more [+] Less [-]Metagenomic exploration of multi-resistance genes linked to microbial attributes in active nonferrous metal(loid) tailings
2021
(Karen A.),
Mine tailings sites are considered as a continuous source of discharged metal(loid)s and residual organic flotation reagents. They are extremely toxic environments representing unique ecological niches for microbial communities. Mine tailings as a source of multi-resistance genes have been poorly investigated. Metagenomic analysis for four active nonferrous metal(loid) tailings sites with different environmental parameters was conducted. The abundance of Thiobacillus, able to tolerate acidity and showing iron- and sulfur/sulfide oxidation capacities, was significantly different (p < 0.05) between acid and neutral tailings sites. Correlation analyses showed that Zn, Pb, TP, Cd, and Cu were the main drivers influencing the bacterial compositions. Multi-metal resistance genes (MRGs) and antibiotic resistance genes (ARGs), such as baca and copA, were found to be co-selected by high concentrations of metal(loid)s tailings. The main contributors to different distributions of MRGs were Thiobacillus and Nocardioides genus, while genera with low abundance (<0.1%) were the main contributors for ARGs. Functional metabolic pathways related to Fe–S metabolism, polycyclic aromatic hydrocarbons (PAHs) degradation and acid stress were largely from Altererythrobacter, Lysobacter, and Thiobacillus, respectively. Such information provides new insights on active tailings with highly toxic contaminants. Short-term metal(loid) exposure of microorganism in active nonferrous metal(loid) tailings contribute to the co-occurrence of ARGs and MRGs, and aggravation of tailings acidification. Our results recommend that the management of microorganisms involved in acid tolerance and metal/antibiotic resistance is of key importance for in-suit treatment of the continuous discharge of tailings with multiple metal(loid) contaminants into impoundments.
Show more [+] Less [-]Diverse effects of accelerating climate change on chemical recovery of alpine lakes from acidic deposition in soil-rich versus scree-rich catchments
2021
Kopáček, Jiří | Kaňa, Jiří | Porcal, Petr | Stuchlík, Evžen
The current recovery of mountain lakes from atmospheric acidification is increasingly affected (both accelerated and/or delayed) by climate change. We evaluated long-term trends in the ionic composition of 30 lakes situated in the alpine zone of the Tatra Mountains, and compared the rates of their recovery with model (MAGIC) simulations done 20 years ago for the 2003–2020 period. The observed recovery was faster than the model forecast, due to greater reductions in acidic deposition than projected. Trends in water composition were further modified by climate change. Rising temperatures increased the length of the growing season and retention of inorganic N and SO₄²⁻ more in soil-rich compared with soil-poor catchments. In contrast, elevated precipitation and an increase in rainfall intensity reduced water residence time in soils, and consequently reduced N retention, especially in soil-poor catchments. It is likely that increases in rainfall intensity and annual number of days without snow, along with air temperatures fluctuating around the freezing point elevated the physical erosion of rocks, especially in high-elevation, steep, and scree-rich areas where rocks are not thermally insulated and stabilized by soils. Weathering of exposed accessory calcite in the eroded granodiorite bedrock was a source of Ca²⁺ and HCO₃⁻, while S-bearing minerals likely contributed to lake water SO₄²⁻ and partly mitigated its deposition-related decrease in scree-rich catchments. The extent of climate effects on changes in the water composition of alpine lakes recovering from acidic deposition thus depended on elevation and cover of soil and scree in catchments. Our results highlight the need for incorporating dominant climate-related process into existing process-based models to increase their reliability in predicting the future development of lake water composition.
Show more [+] Less [-]Organic-matter decomposition as a bioassessment tool of stream functioning: A comparison of eight decomposition-based indicators exposed to different environmental changes
2021
Ferreira, Verônica | Silva, João | Cornut, Julien | Sobral, Olímpia | Bachelet, Quentin | Bouquerel, Jonathan | Danger, Michael
Organic-matter decomposition has long been proposed as a tool to assess stream functional integrity, but this indicator largely depends on organic-matter selection. We assessed eight decomposition-based indicators along two well-known environmental gradients, a nutrient-enrichment gradient (0.2–1.4 mg DIN/L) in central Portugal and an acidification gradient (pH: 4.69–7.33) in north-eastern France to identify the most effective organic-matter indicator for assessing stream functional integrity. Functional indicators included natural leaf litter (alder and oak) in 10-mm and 0.5-mm mesh bags, commercial tea (Lipton green and rooibos teas in 0.25-mm mesh bags), wood sticks (wood tongue depressors) and cotton strips. Biotic indices based on benthic macroinvertebrates (IPtIN for Portugal and IBGN for France) were calculated to compare the effectiveness of structural and functional indicators in detecting stream impairment and to assess the relationship between both types of indicators. The effectiveness of organic-matter decomposition rates as a functional indicator depended on the stressor considered and the substrate used. Decomposition rates generally identified nutrient enrichment and acidification in the most acidic streams. Decomposition rates of alder and oak leaves in coarse-mesh bags, green and rooibos teas and wood sticks were positively related with pH. Only decomposition rates of rooibos tea and wood sticks were related with DIN concentration; decomposition rates along the nutrient-enrichment gradient were confounded by differences in shredder abundance and temperature among streams. Stream structural integrity was good to excellent across streams; the IPtIN index was unrelated to DIN concentration, while the IBGN index was positively related with pH. The relationships between decomposition rates and biotic indices were loose in most cases, and only decomposition rates of alder leaves in coarse-mesh bags and green tea were positively related with the IBGN. Commercial substrates may be a good alternative to leaf litter to assess stream functional integrity, especially in the case of nutrient enrichment.
Show more [+] Less [-]Long-term variability in base cation, sulfur and nitrogen deposition and critical load exceedance of terrestrial ecosystems in China
2021
Zhao, Wenxin | Zhao, Yu | Ma, Mingrui | Chang, Ming | Duan, Lei
The rapid development of China's industrial economy and implementation of air pollution controls have led to great changes in sulfur (S), nitrogen (N) and base cation (BC) deposition in the past three decades. We estimated China's anthropogenic BC emissions and simulated BC deposition from 1985 to 2015 with a five-year interval using a multilayer Eulerian model. Deposition of S and N from 2000 to 2015 with a five-year interval was simulated with the EMEP MSC-W model and the Multi-resolution Emission Inventory of China (MEIC). The critical load (CL) and its exceedance were then calculated to evaluate the potential long-term acidification risks. From 1985 to 2005, the BC deposition in China was estimated to have increased by 16 % and then decreased by 33 % till 2015. S deposition was simulated to increase by 49 % from 2000 to 2005 and then decrease by 44 % in 2015, while N deposition increased by 32 % from 2000 to 2010 with a limited reduction afterward. The maximum CL of S was found to increase in 67 % of mainland China areas from 1985 to 2005 and to decline in 55 % of the areas from 2005 to 2015, attributed largely to the changed BC deposition. Consistent with the progress of national controls on SO₂ and NOX emissions, the CL exceedance of S increased from 2.9 to 4.6 Mt during 2000–2005 and then decreased to 2.5 Mt in 2015, while that of N increased from 0.4 in 2000 to 1.2 Mt in 2010 and then decreased to 1.1 Mt in 2015. The reduced BC deposition due to particle emission controls partially offset the benefit of SO₂ control on acidification risk reduction in the past decade. It demonstrates the need for a comprehensive strategy for multi-pollutant control against soil acidification.
Show more [+] Less [-]Multiple isotopic tracing for sulfate and base cation sources of precipitation in Hangzhou city, Southeast China: Insights for rainwater acidification mechanism
2021
Wu, Yao | Liu, Wenjing | Xu, Yifu | Xu, Zhifang | Zhou, Xiaode | Zhou, Lian
Acid deposition has been regarded as a serious factor in the deteriorative water environment and ecosystems. Despite the powerful acid emission control measures have been implemented by the Chinese government, many areas (especially Southeast China) are still suffering from acid deposition. The chemical and isotopic (δ³⁴S and ⁸⁷Sr/⁸⁶Sr) compositions of rainwater in Hangzhou, a typical megacity in Southeast China with serious acid rain problem, for one year were studied with the aim to better constrain potential sources and explore the causes of rainwater acidification. Most rainwater samples were acidic, with a VWM pH value of 4.65. SO₄²⁻ was the dominant anion and the main acid ion in rainwater. Sulfur isotope and the quantity equilibrium model revealed that sea salt, crustal, biogenic, and anthropogenic sulfur represented 2.3%, 0.1%, 16.7%, and 80.8% of the SO₄²⁻ source in rainwater, respectively. The back trajectory and strontium isotopes indicated that the base cations (BCs) in rainwater originated mainly from anthropogenic sources. The relatively low neutralizing capacity caused by limited BCs input and emission control measures undermines some efforts to reduce rainwater acidity. This case study demonstrated that a valuable tool to probe the source of acid rain and unravel the mechanism of rainwater acidification can be provided by multiple lines of evidence, including rainwater chemical compositions, stable sulfur isotopes, and stable strontium isotopes.
Show more [+] Less [-]Effect of nitrite addition on the two-phase anaerobic digestion of waste activated sludge: Optimization of the acidogenic phase and influence mechanisms
2020
To simultaneously achieve biological denitrification and bio-energy recovery from sludge, the effects of nitrite on the two-phase anaerobic digestion (AD) of waste activated sludge were explored. Herein, effects of nitrite on the acidogenic phase are optimized, and the corresponding influence mechanisms are investigated. The experimental results show that the optimal nitrite treatment conditions for improving the acidogenic phase are an initial pH of 8.0, a nitrite addition concentration of 500 mg NO₂⁻-N·L⁻¹, and a fermentation time of six days. By comparing the effects of nitrite and nitrate on the acidogenic phase, it was found that it was the nitrite, not the nitrate, that significantly enhanced the sludge organic solubilization, hydrolysis, and acidification, which are primarily attributed to the redox property of nitrite. Based on an analysis of different forms of soluble nitrogen concentrations, there was no obvious accumulation of nitrite or nitrate during the acidogenic phase. An analysis of the methane production and the volatile solid (VS) degradation during the two-phase AD revealed that the nitrite improved the methane production from the methanogenic phase and enhanced the VS degradation of sludge during the entire two-phase AD process. These findings could provide references for simultaneously treating nitrite-rich wastewater and improving anaerobic sludge digestion via two-phase system.
Show more [+] Less [-]The impacts of intensive mining on terrestrial and aquatic ecosystems: A case of sediment pollution and calcium decline in cool temperate Tasmania, Australia
2020
Beck, K.K. | Mariani, M. | Fletcher, M.-S. | Schneider, L. | Aquino-López, M.A. | Gadd, P.S. | Heijnis, H. | Saunders, K.M. | Zawadzki, A.
Mining causes extensive damage to aquatic ecosystems via acidification, heavy metal pollution, sediment loading, and Ca decline. Yet little is known about the effects of mining on freshwater systems in the Southern Hemisphere. A case in point is the region of western Tasmania, Australia, an area extensively mined in the 19th century, resulting in severe environmental contamination. In order to assess the impacts of mining on aquatic ecosystems in this region, we present a multiproxy investigation of the lacustrine sediments from Owen Tarn, Tasmania. This study includes a combination of radiometric dating (¹⁴C and ²¹⁰Pb), sediment geochemistry (XRF and ICP-MS), pollen, charcoal and diatoms. Generalised additive mixed models were used to test if changes in the aquatic ecosystem can be explained by other covariates. Results from this record found four key impact phases: (1) Pre-mining, (2) Early mining, (3) Intense mining, and (4) Post-mining. Before mining, low heavy metal concentrations, slow sedimentation, low fire activity, and high biomass indicate pre-impact conditions. The aquatic environment at this time was oligotrophic and dystrophic with sufficient light availability, typical of western Tasmanian lakes during the Holocene. Prosperous mining resulted in increased burning, a decrease in landscape biomass and an increase in sedimentation resulting in decreased light availability of the aquatic environment. Extensive mining at Mount Lyell in the 1930s resulted in peak heavy metal pollutants (Pb, Cu and Co) and a further increase in inorganic inputs resulted in a disturbed low light lake environment (dominated by Hantzschia amphioxys and Pinnularia divergentissima). Following the closure of the Mount Lyell Co. in 1994 CE, Ca declined to below pre-mining levels resulting in a new diatom assemblage and deformed diatom valves. Therefore, the Owen Tarn record demonstrates severe sediment pollution and continued impacts of mining long after mining has stopped at Mt. Lyell Mining Co.
Show more [+] Less [-]The mechanism for inhibiting acidification of variable charge soils by adhered Pseudomonas fluorescens
2020
Nkoh, Jackson Nkoh | Yan, Jing | Xu, Ren-Kou | Shi, Ren-yong | Hong, Zhi-neng
Acidification in variable charge soils is on the rise due to increased acid deposition and use of nitrogenous fertilizers. The associated low pH and cation exchange capacity make the soils prone to depleted base cations and increased levels of Al³⁺. Consequently, Al toxicity to plants and soil infertility decrease crop yield. This study was designed to investigate the effect of Pseudomonas fluorescens on the acidification of two Ultisols. The simulated acidification experiment demonstrated that the pH of bacteria-treated soil was higher than that of control under similar conditions, suggesting that the adhered bacteria inhibited soil acidification. This observation was attributed to the association of organic anions (RCOO⁻ or RO⁻) on bacteria with H⁺ to form neutral molecules (RCOOH or ROH) and reducing the activity of H⁺ in solution. The bacteria also inhibited the increase in soil soluble Al and exchangeable Al during soil acidification. The adhesion of bacteria on the soils increased soil effective cation exchange capacity (ECEC) and exchangeable base cations at each pH compared to control. The release of exchangeable base cations from bacteria-treated soil, and the decrease in soil ECEC and exchangeable base cations with decreasing pH confirmed that protonation of organic anions on adhered bacteria was mainly responsible for the inhibition of soil acidification. The change of zeta potential of the bacteria with pH and the ART-FTIR analysis at various pH provided more evidence for this mechanism. Therefore, the bacteria in variable charge soils played an important role in retarding soil acidification.
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