This study has evaluated urban habitat quality by studying specific leaf area (SLA) and stomatal characteristics of the common herb Plantago lanceolata L. SLA and stomatal density, pore surface and resistance were measured at 169 locations in the city of Gent (Belgium), distributed over four land use classes, i.e., sub-urban green, urban green, urban and industry. SLA and stomatal density significantly increased from sub-urban green towards more urbanised land use classes, while the reverse was observed for stomatal pore surface. Stomatal resistance increased in the urban and industrial land use class in comparison with the (sub-) urban green, but differences between land use classes were less pronounced. Spatial distribution maps for these leaf characteristics showed a high spatial variation, related to differences in habitat quality within the city. Hence, stomatal density and stomatal pore surface are assumed to be potentially good bio-indicators for urban habitat quality. Stomatal characteristics of Plantago lanceolata can be used for biomonitoring of urban habitat quality.

Air pollution is a major contributor to several respiratory problems, it affects the whole population in general but children are more susceptible. Exposure to automobile exhaust is associated with increased respiratory symptoms and may impair lung function in children. In view of this, the study was conducted among the children of Delhi, the capital city of India, where ambient air quality was much above the National Ambient Air Quality Standards. The study was conducted in children aged 9-17 years. Pulmonary function test was carried out following the guideline of American Thoracic Society using a portable, electronic spirometer. Air quality data was collected from Central and State Pollution Control Boards. In addition, the level of particulate matter in indoor air was measured by portable laser photometer. Lung function was reduced in 43.5% schoolchildren of the urban area compared with 25.7% of control group. The urban children had increased prevalence of restrictive, obstructive, as well as combined type of lung functions deficits. Besides higher prevalence, the magnitude of lung function deficits was also much more in them. After controlling potential confounders like season, socioeconomic conditions and ETS, PM10 level in ambient air was found to be associated with restrictive (OR = 1.35, 95% CI 1.07-1.58), obstructive (OR = 1.45, 95% CI 1.16-1.82), and combined type of lung function deficits (OR = 1.74, 95% CI 1.37-2.71) in children. Spearman's rank correlation test reaffirmed the association. The study confirms that the level of air pollution is affecting the children.

Modern European cities are characterized by high particulate matter (PM) concentrations. Unfortunately, the number of stations monitoring air pollution, especially PM, is never sufficient for the overall representation of the problem. In the present work, an inexpensive outdoor passive sampler (based on an indoor passive sampler) was developed and assembled in an effort to provide the means to extend current PM monitoring networks. The uncertainty of the sampler was tested in vitro and in vivo. Twenty such outdoor passive samplers were assembled and installed at specific locations in the Greater Thessaloniki Area and measurements of PM were carried out. The results were in good agreement with the official monitoring stations. In addition, they revealed the aggravated air quality in the center of the city and in the west suburbs.

Ambient aerosol concentrations have been implicated in human health effects, in visibility reduction in urban and regional areas, in acid deposition and in perturbing the Earth’s radiation balance. The main concern of the air quality managers is to achieve compliance to the established air quality standards (AQS). As AQS are exceeded in numerous sites worldwide, it is essential to reduce the emissions. Having decided which statistical distribution fits well to the PM10 parent distribution, it is feasible to estimate the reduction in emissions that is required in order to meet AQS. In this study, it is verified that the PM10 concentration distribution can be adequately simulated by lognormal distribution, a conclusion drawn by the calculation of several statistical indexes. The study area is the city of Volos in central Greece, which is experiencing an unpleasant situation concerning the levels of PM10 pollution. The probability density function of lognormal distribution is capable to predict the number of days when the European Union (EU) AQS for PM10 concentration are exceeded in Volos area. Furthermore, the minimum reduction in current emission sources of PM10 required in order to meet the air quality regulations that are established by the EU is calculated for the study area and is found to be ~33%. The results could be utilized as reference for air pollution control strategy.

Assessing air quality in street canyons is a crucial concern, as the highest pollution levels and threshold exceedances are usually experienced within this kind of urban streets. A brief overview based on experimental studies and modelling techniques undertaken in literature is presented, including characteristic features affecting wind flow and pollutant dispersion within street canyons. In this work, a numerical street canyon model intercomparison has been performed in a typical urban canyon in Florence, Italy. In particular, STREET, Canyon Plume Box Model (CPBM) and Operational Street Pollution Model (OSPM) have been applied to compute the street-level 1-h carbon monoxide (CO) concentrations. In addition, the CALINE4 model has been applied to test the site morphology. Input data cover a 1-year time period and include meteorological observations as well as measured traffic volumes and driving speeds. Hourly road emissions have been calculated using the COPERT methodology taking into account vehicle fleet, traffic flows and driving speed, as well as ambient temperature to account for cold overemissions. A preliminary experimental data analysis has been carried out in order to investigate the dependence of observed CO concentrations on meteorological and traffic parameters. Hourly CO concentrations observed over the full year have been used to compare the STREET, CPB and OSP models, resulting in a detailed statistical analysis carried out by wind sector as well as on a seasonal basis.

This study proposes a two-phase optimization model for regional air pollution control. To predict the pollutant concentrations at receptor zones, an interval Gaussian plume model is advanced to facilitate the generation of optimal pollution control policies. Results from the case study indicate satisfactory performance of the proposed model in handling uncertainties in parameters expressed as intervals and in stipulations associated with pollutant emission and ambient air quality. Compared with conventional models, it has advantages of generating compromised management strategies according to decision makers' preference. This would be useful when the guarantee of satisfying all constraints is inapplicable or too costly. The proposed model is capable of identifying key factors and/or input conditions that may intensely affect system outputs and thus facilitating decision makers in adjusting current system status to benefit future management. The results also reveal a significantly enhanced satisfactory level would be obtained compared with conventional “single-phase”-based optimization models.

Polycyclic aromatic hydrocarbons (PAHs); their derivatives nitro, and methyl-PAHs; n-alkanes; and organic acids were investigated in the aerosol samples collected during two field campaigns conducted at three sampling stations in an industrialized city in southern Italy. The main sources affecting the atmosphere and its toxicity were investigated by means of the diagnostic ratios of: specific particulate-phase PAHs, marker compounds among nitro-PAHs, alkanes, and acids, the dominant wind direction, daily and seasonal abundance of carcinogenic organic substances. The potential importance of the non-regulated pollutants to assess the air quality was confirmed; in fact the carcinogenic organic compounds showed to have scarce correlation with particulate matter (PM) concentration. An exceptionally high variability of toxic compounds at a daily scale was due to meteorological condition causing periods of extremely high pollution levels.

Background, aim, and scope To stimulate the national economy, a so-called “gold week” comprising May Day and National Day has been put in force by the government, and the first golden-week holiday began on October 1, 1999. Statistical data show that about 15,000 visitors were received each day by Emperor Qin's Terra-Cotta Museum during just such a gold week period. To evaluate the effects of tourism on indoor air, airborne samples were collected by the sedimentation plate method for 5 min during the “Oct. 1” gold week period of 2006, and both composition and changes of airborne bacteria and fungi in indoor/outdoor air in the museums were investigated. Materials and methods Airborne microbes were simultaneously collected by means of gravitational sedimentation on open Petri dishes. Three parallel samples were collected at the same time each day, and samples were subsequently incubated in the lab. Microbiology media were prepared before each experiment by a professional laboratory. Concentrations were calculated and presented as average data of colony-forming units per cubic meter of air (CFU/m³). Results The results show that (1) 13 bacterial genera and eight genera of fungi were identified from indoor and outdoor air at Emperor Qin's Terra-Cotta Museum during “Oct. 1” gold week in 2006. The bacterial groups occupied 61%, the fungi groups occupied 36%, and others occupied 3% of the total number of isolated microorganism genera. (2) As for the comparison of indoor and outdoor samples, the average concentrations of fungi were higher during the afternoon (13:00) than for the morning (09:00). The average concentrations of bacteria in indoor air were higher during the afternoon (13:00) than for the morning (9:00), and in outdoor air, they were lower during the afternoon (13:00) than for the morning (9:00). (3) The average concentrations of five dominant groups of bacteria and three dominant groups of fungi were higher during the afternoon (13:00) than for the morning (9:00) in the indoor air, but the average concentrations of fungi were higher and those of bacteria were lower during the afternoon than for the morning, for outdoor air. (4) As for the comparison of indoor samples, the bacterial daily concentrations and fungal daily concentrations were higher during the afternoon (13:00) than those for the mornings (9:00) over the 10 days. For the comparison of outdoor samples, the bacterial concentration was lower, and the fungal concentrations were higher during the afternoon (13:00) than those for the morning (9:00) over the 10 days. Discussion The results also show that the numbers of airborne bacteria and fungi had a daily character in indoor air and were higher in the afternoon. The airborne microbe concentrations were found to be similar to residential indoor values from other reports; the indoor museum maximum of microbial concentrations was 90 CFU/m³ and did not exceed the Chinese indoor bioaerosol guideline. However, microorganisms may fall on the surface of display items as a result of particle sedimentation and would, as such, be capable of degrading objects by way of their secretions, e.g., enzymes and organic acids. Therefore, the right steps should be taken to prevent any deterioration in the quality of displayed artifacts. Conclusions The results show that museum air was affected by human activity; therefore, it is imperative that the number of visitors be strictly limited and that windows be opened regularly to avoid air pollution. Recommendations and perspectives The data provide a significant scientific basis for indoor air quality control and museum scientific management. It is recommended that the number of visitors be strictly limited.

Background and purpose In Pakistan, almost 70% of the population lives in rural areas. Ninety-four percent of households in rural areas and 58% in urban areas depend on biomass fuels (wood, dung, and agricultural waste). These solid fuels have poor combustion efficiency. Due to incomplete combustion of the biomass fuels, the resulting smoke contains a range of health-deteriorating substances that, at varying concentrations, can pose a serious threat to human health. Indoor air pollution accounts for 28,000 deaths a year and 40 million cases of acute respiratory illness. It places a significant economic burden on Pakistan with an annual cost of 1% of GDP. Despite the mounting evidence of an association between indoor air pollution and ill health, policy makers have paid little attention to it. This review analyzes the existing information on levels of indoor air pollution in Pakistan and suggests suitable intervention methods. Methods This review is focused on studies of indoor air pollution, due to biomass fuels, in Pakistan published in both scientific journals and by the Government and international organizations. In addition, the importance of environmental tobacco smoke as an indoor pollutant is highlighted. Results Unlike many other developing countries, there are no long-term studies on the levels of indoor air pollution. The limited studies that have been undertaken indicate that indoor air pollution should be a public health concern. High levels of particulate matter and carbon monoxide have been reported, and generally, women and children are subject to the maximum exposure. There have been a few interventions, with improved stoves, in some areas since 1990. However, the effectiveness of these interventions has not been fully evaluated. Conclusion Indoor air pollution has a significant impact on the health of the population in Pakistan. The use of biomass fuel as an energy source is the biggest contributor to poor indoor air quality followed by smoking. In order to arrest the increasing levels of indoor pollution, there is a dire need to recognize it as a major health hazard and formulate a national policy to combat it. An integrated effort, with involvement of all stakeholders, could yield promising results. A countrywide public awareness campaign, on the association of indoor air pollution with ill health, followed by practical intervention would be an appropriate approach. Due to the current socioeconomic conditions in the country, development and adoption of improved cooking stoves for the population at large would be the most suitable choice. However, the potential of biogas as a fuel should be explored further, and modern fuels (natural gas and LPG) need to be accessible and economical. Smoking in closed public spaces should be banned, and knowledge of the effect of smoking on indoor air quality needs to be quantified.

Introduction Photochemical ozone pollution of the lower troposphere (LT) is a very complex process involving meteorological, topographic emissions and chemical parameters. Ozone is considered the most important air pollutant in rural, suburban and industrial areas of many sites in the world since it strongly affects human health, vegetation and forest ecosystems, and its increase during the last decades has been significant. In addition, ozone is a greenhouse gas that contributes to climate change. For these reasons, it is necessary to carry out investigations that determine the behaviour of ozone at different locations. The aim of this work is to understand the levels and temporal variations of surface ozone in an industrial-urban region of the Southwest Iberian Peninsula. Materials and methods The study is based on ozone hourly data recorded during a 6-year period, 2000 to 2005 at four stations and meteorological data from a coastal station. The stations used were El Arenosillo and Cartaya—both coastal stations, Huelva—an urban site and Valverde—an inland station 50 km away from the coastline. The general characteristics of the ozone series, seasonal and daily ozone cycles as well as number of exceedances of the threshold established in the European Ozone Directive have been calculated and analysed. Results Analysis of the meteorological data shows that winter-autumn seasons are governed by the movement of synoptic weather systems; however, in the spring-summer seasons, both synoptic and mesoescale conditions exist. Average hourly ozone concentrations range from 78.5 ± 0.1 μg m⁻³ at Valverde to 57.8 ± 0.2 μg m⁻³ at Huelva. Ozone concentrations present a seasonal variability with higher values in summer months, while in wintertime, lower values are recorded. A seasonal daily evolution has also been found with minimum levels around 08:00 UTC, which occurs approximately 1-1.5 h after sunrise, whereas the maximum is reached at about 16:00 UTC. Furthermore, during summer, the maximum value at El Arenosillo and Valverde stations remains very uniformed until 20:00 UTC. These levels could be due to the photochemical production in situ and also to the horizontal and vertical ozone transport at El Arenosillo from the reservoir layers in the sea and in the case of Valverde, the horizontal transport, thanks to the marine breeze. Finally, the data have been evaluated relative to the thresholds defined in the European Ozone Directive. The threshold to protect human health has been exceeded during the spring and summer months mainly at El Arenosillo and Valverde. The vegetation threshold has also been frequently exceeded, ranging from 131 days at Cartaya up to 266 days at Valverde. Discussion The results in the seasonal and daily variations demonstrate that El Arenosillo and Valverde stations show higher ozone concentrations than Cartaya and Huelva during the spring and summer months. Under meteorological conditions characterized by land-sea breeze circulation, the daytime sea breeze transports the emissions from urban and industrial sources in the SW further inland. Under this condition, the area located downwind to the NE is affected very easily by high ozone concentrations, which is the case for the Valverde station. Nevertheless, according to this circulation model, the El Arenosillo station located at the coast SE from these sources is not directly affected by their emissions. The ozone concentrations observed at El Arenosillo can be explained by the ozone residual layer over the sea, similar to other coastal sites in the Mediterranean basin. Conclusions The temporal variations of the ozone concentrations have been studied at four measurement sites in the southwest of the Iberian Peninsula. The results obtained point out that industrial and urban emissions combined with specific meteorological conditions in spring and summer cause high ozone levels which exceed the recommended threshold limits and could affect the vegetation and human health in this area. Recommendations and perspectives This work is the first investigation related to surface ozone in this region; therefore, the results obtained may be a useful tool to air quality managers and policy-makers to apply possible air control strategies towards a reduction of ozone exceedances and the impact on human health and vegetation. Due to the levels, variability and underlying boundary layer dynamics, it is necessary to extend this research in this geographical area with the purpose of improving the understanding of photochemical air pollution in the Western Mediterranean Basin and in the south of the Iberian Peninsula.