The work evaluates the urban snow cover pollution and determines the level of the city influence on the pollution of the urban atmosphere with major ions (ammonium, nitrite, nitrate, chloride, sulfate, phosphate, sodium, potassium, magnesium, calcium) during the winter period (on the case study of Barnaul city, 2014-2019). The priority ions that determine the high pollution of the urban atmosphere in winter are (nitrite, chloride, sodium), the sources of which are the exhaust of motor vehicles (nitrite) and the using of anti-ice reagents (chloride, sodium). The study showed an increase of the major ions in the urban snow cover (with the exception of nitrate ion) by more than two times compared with the regional and more than six times with the global natural background. To study the spatial features of the snow cover pollution interpolation surfaces of the spatial distribution of priority ions in the study area were constructed.

Predicting the transfer of contaminants in soils is often hampered by lacking validation of mathematical models. Here, we applied Hydrus-2D software to three agricultural soils for simulating the 1900–2005 changes of zinc and lead concentration profiles derived from industrial atmospheric deposition, to validate the tested models with plausible assumptions on past metal inputs to reach the 2005 situation. The models were set with data from previous studies on the geochemical background, estimated temporal metal deposition, and the 2005 metal distributions. Different hypotheses of chemical reactions of metals with the soil solution were examined: 100% equilibrium or partial equilibrium, parameterized following kinetic chemical extractions. Finally, a two-site model with kinetic constant values adjusted at 1% of EDTA extraction parameters satisfactory predicted changes in metal concentration profiles for two arable soils. For a grassland soil however, this model showed limited applicability by ignoring the role of earthworm activity in metal incorporation.

Soil contamination due to atmospheric deposition of metals originating from smelters is a global environmental problem. A common problem associated with this contamination is the discrimination between anthropic and natural contributions to soil metal concentrations: In this context, we investigated the characteristics of soil contamination in the surrounding area of a world class smelter. We attempted to combine several approaches in order to identify sources of metals in soils and to examine contamination characteristics, such as pollution level, range, and spatial distribution. Soil samples were collected at 100 sites during a field survey and total concentrations of As, Cd, Cr, Cu, Fe, Hg, Ni, Pb, and Zn were analyzed. We conducted a multivariate statistical analysis, and also examined the spatial distribution by 1) identifying the horizontal variation of metals according to particular wind directions and distance from the smelter and 2) drawing a distribution map by means of a GIS tool. As, Cd, Cu, Hg, Pb, and Zn in the soil were found to originate from smelter emissions, and As also originated from other sources such as abandoned mines and waste landfill. Among anthropogenic metals, the horizontal distribution of Cd, Hg, Pb, and Zn according to the downwind direction and distance from the smelter showed a typical feature of atmospheric deposition (regression model: y = y0 + αe−βx). Lithogenic Fe was used as an indicator, and it revealed the continuous input and accumulation of these four elements in the surrounding soils. Our approach was effective in clearly identifying the sources of metals and analyzing their contamination characteristics. We believe this study will provide useful information to future studies on soil pollution by metals around smelters.

International audience | This paper looks at experiential feedback and the technical and scientific challenges tied to the MERITE-HIPPOCAMPE cruise that took place in the Mediterranean Sea in spring 2019. This cruise proposes an innovative approach to investigate the accumulation and transfer of inorganic and organic contaminants within the planktonic food webs. We present detailed information on how the cruise worked, including 1) the cruise track and sampling stations, 2) the overall strategy, based mainly on the collection of plankton, suspended particles and water at the deep chlorophyll maximum, and the separation of these particles and planktonic organisms into various size fractions, as well as the collection of atmospheric deposition, 3) the operations performed and material used at each station, and 4) the sequence of operations and main parameters analysed. The paper also provides the main environmental conditions that were prevailing during the campaign. Lastly, we present the types of articles produced based on work completed by the cruise that are part of this special issue.

International audience | Worldwide there is concern about the continuing release of persistent organic pollutants (POPs) into the environment. In this study we review the application of mosses as biomonitors of atmospheric deposition of POPs. Examples in the literature show that mosses are suitable organisms to monitor spatial patterns and temporal trends of atmospheric concentrations or deposition of POPs. These examples include polycyclic aromatic hydrocarbons (PAHs), polychlorobiphenyls (PCBs), dioxins and furans (PCDD/Fs), and polybrominated diphenyl ethers (PBDEs). The majority of studies report on PAHs concentrations in mosses and relative few studies have been conducted on other POPs. So far, many studies have focused on spatial patterns around pollution sources or the concentration in mosses in remote areas such as the polar regions, as an indication of long-range transport of POPs. Very few studies have determined temporal trends or have directly related the concentrations in mosses with measured atmospheric concentrations and/or deposition fluxes.

The input of trace elements via atmospheric deposition towards industrial, urban, traffic, and rural areas is quite different and depends on the intensity of the anthropogenic activity. A comparative study between the element deposition fluxes in four sampling sites (industrial, urban, traffic, and rural) of the Cantabria region (northern Spain) has been performed. Sampling was carried out monthly using a bulk (funnel bottle) sampler. The trace elements, As, Cd, Cr, Cu, Mn, Mo, Ni, Pb, Ti, Zn, and V, were determined in the water soluble and insoluble fractions of bulk deposition samples. The element deposition fluxes at the rural, urban, and traffic sites followed a similar order (Zn>Mn>>Cu=Ti>Pb>V=Cr>Ni>>As=Mo>Cd). The most enriched elements were Cd, Zn, and Cu, while V, Ni, and Cr were less enriched. An extremely high deposition of Mn was found at the industrial site, leading to high enrichment factor values, resulting from the presence of a ferro-manganese/silicomanganese production plant in the vicinity of the sampling site. Important differences were found in the element solubilities in the studied sites; the element solubilities were higher at the traffic and rural sites, and lower at the urban and industrial sites. For all sites, Zn and Cd were the most soluble elements, whereas Cr and Ti were less soluble. The inter-site correlation coefficients for each element were calculated to assess the differences between the sites. The rural and traffic sites showed some similarities in the sources of trace elements; however, the sources of these elements at the industrial and rural sites were quite different. Additionally, the element fluxes measured in the insoluble fraction of the bulk atmospheric deposition exhibited a good correlation with the daily traffic volume at the traffic site. | The authors are grateful for the financial support from the CTM 2010-16068 (Spanish Ministry of Science and Innovation) and CTM 2013-43904 R (Spanish Ministry of Economy and Competitiveness) projects. The “Consejería de Medio Ambiente” from the Cantabria Government is also acknowledged for sending the report on the background levels of heavy metals and trace elements in soils in the Cantabria region. The authors are also grateful to “Ayuntamiento de Camargo” for helping us with the sampling site of Maliaño.

International audience | Calcium dissolved deposition shows an unusual spatial structure in France, probably due to the contribution of southern air masses from Mediterranean Sea and Saharan desert. These masses are often loaded with terrigenous particles that contain carbonates. However, no precise relationship has been quantified between dissolved Ca and mineral dust deposition (MDD). The database of the French network RENECOFOR, gathering atmospheric deposition <0.45 mu m in 27 sites near forests during 18 years, was used to determine the non-sea-salt atmospheric deposition over France. This study (1) explores the relationship between dissolved components to decipher their origin in atmospheric deposition nearby forests and (2) tests the use of dissolved Ca and Mg as proxies for MDD. In the RENECOFOR database, non-sea-salt Ca (nssCa) preferentially deposited between May and August. MDD observed in RENECOFOR was synchronic with high nssCa deposition, particularly in June 2008, when air mass highly loaded with Saharan dust covered France. The dissolution of this mineral dust likely contributed to the nssCa deposition of this period and suggested a relationship between the depositions of nssCa and MDD. Then, MDD was specifically sampled with dissolved deposition in four sampling sites. Encouraging relationships were found between MDD and the depositions of nssMg and nssCa, suggesting that the latter could be used as a proxy for MDD in regions where it is not monitored, and in a retrospective approach in order to calculate nutrient fluxes.

Salt marsh estuaries serve as sources and sinks for nutrients and elements to and from estuarine water, which enhances and alleviates watershed fluxes to the coastal ocean. We assessed sources and sinks of mercury in the intertidal Plum Island Sound estuary in Massachusetts, the largest salt marsh estuary of New England, using 25-km spatial water sampling transects. Across all seasons, dissolved (FHg) and total (THg) mercury concentrations in estuarine water were highest and strongly enhanced in upper marshes (1.31 ± 0.20 ng L⁻¹ and 6.56 ± 3.70 ng L⁻¹, respectively), compared to riverine Hg concentrations (0.86 ± 0.17 ng L⁻¹ and 0.88 ± 0.34 ng L⁻¹, respectively). Mercury concentrations declined from upper to lower marshes and were lowest in ocean water (0.38 ± 0.10 ng L⁻¹ and 0.56 ± 0.25 ng L⁻¹, respectively). Conservative mixing models using river and ocean water as endmembers indicated that internal estuarine Hg sources strongly enhanced estuarine water Hg concentrations. For FHg, internal estuarine Hg contributions were estimated at 26 g yr⁻¹ which enhanced Hg loads from riverine sources to the ocean by 44%. For THg, internal sources amounted to 251 g yr⁻¹ and exceeded riverine sources six-fold. Proposed sources for internal estuarine mercury contributions include atmospheric deposition to the large estuarine surface area and sediment re-mobilization, although sediment Hg concentrations were low (average 23 ± 2 μg kg⁻¹) typical of uncontaminated sediments. Soil mercury concentrations under vegetation, however, were ten times higher (average 200 ± 225 μg kg⁻¹) than in intertidal sediments suggesting that high soil Hg accumulation might drive lateral export of Hg to the ocean. Spatial transects of methylated Hg (MeHg) showed no concentration enhancements in estuarine water and no indication of internal MeHg sources or formation. Initial mass balance considerations suggest that atmospheric deposition may either be in similar magnitude, or possibly exceed lateral tidal export which would be consistent with strong Hg accumulation observed in salt marsh soils sequestering Hg from current and past atmospheric deposition.

Smelting activities are considered as the primary cause of heavy metal (HM) accumulation in soils, and the human health around the smelter has been a great concern worldwide. In this study, a total of 242 agricultural soil samples were collected around a large scale Pb/Zn smelter in China, and eight HMs (As, Cd, Cr, Cu, Hg, Ni, Pb and Zn) were analyzed to assess HMs status, ecological -health risks, and identify source. Monte Carlo simulation was utilized to evaluate the probabilistic health risks, and positive matrix factorization (PMF) was employed to identify sources. The results revealed the average contents of five heavy metals (Cd 5.28 mg/kg, Pb 203.36 mg/kg, Hg 0.39 mg/kg, Zn 293.45 mg/kg, Cu 37.14 mg/kg) are higher than their background values in Hunan province. Cd had the highest mean pollution index (PI) of 41.8 and the greatest average ecological risk index (Eᵣ) of 1256.34, indicating that Cd was the primary enriched pollutant and had a higher ecological risk than other HMs. The mean hazard index (HI) through exposure to eight HMs was 2.95E-01 and 9.74E-01 for adults and children, respectively, with 35.94% of HI values for children exceeding the risk threshold of 1. Moreover, the mean total cancer risks (TCR) were 2.75E-05 and 2.37E-04 for adults and children, respectively, with 75.48% of TCR values for children exceeding the guideline value of 1E-04. In addition, the positive matrix factorization results showed smelting activities, natural sources, agricultural activities and atmospheric deposition were the three sources in soils, with the contribution rate of 48.62%, 22.35%, and 29.03%, respectively. The uncertainty analysis of the PMF indicated that the three-factor solution is reliable. This work will provide scientific reference for the comprehensive prevention of soil HM pollution adjacent to the large smelter.

Trace metal (loid) contamination in the atmosphere is widely monitored, but there is a gap in understanding its long-term patterns, especially in North China, which is currently a global contamination hotspot mainly caused by heavy industry emissions and coal combustion. Herein, historical trends of atmospheric As, Cd, Cr, Cu, Hg, Ni, Pb and Zn contamination in North China over the past ∼500 years are comparatively studied with sediment cores from two subalpine lakes (Gonghai and Muhai). Arsenic, Pb, Cd and Hg were main pollutants according to Pb isotopes and enrichment factors. Mercury contamination has increased continuously since the late 1800s and increasing As, Pb and Cd contamination started in the 1950s in Gonghai. In contrast, the contamination in Muhai lagged two decades for As, Cd and Pb and a half-century for Hg behind that in Gonghai, although the trends were similar. This contamination lag was attributed to the low sensitivity of Muhai sediment to early weak atmospheric metal contamination under 2.1-fold higher detrital sedimentation. As, Pb and Cd contamination has intensified since the 1980s, and the metals showed similar sedimentary fluxes in the cores. However, sedimentary fluxes of Hg contamination were 3.4-fold higher in Gonghai than in Muhai due to combination with organic matter. No obvious Cr, Cu and Ni contamination in the cores was mainly because of the low atmospheric deposition from anthropogenic sources relative to detrital input, although some of their atmospheric emissions were higher than those of As, Cd and Hg. Atmospheric As, Pb and Cd contamination was mainly from domestic sources of coal combustion and nonferrous smelting. Mercury contamination was mainly from global and Asian sources in the first half of the 20th century, and domestic emissions gradually dominated Hg contamination after the mid-1900s.