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Spatial distribution of PAH concentrations and stable isotope signatures (δ13C, δ15N) in mosses from three European areas - Characterization by multivariate analysis
2014
Foan, Louise | Leblond, Sébastien | Thöni, Lotti | Raynaud, Christine | Santamaria, Jesus Miguel | Sebilo, Mathieu | Simon, Valérie | Chimie Agro-Industrielle (CAI) ; Institut National de la Recherche Agronomique (INRA)-Ecole nationale supérieure des ingénieurs en arts chimiques et technologiques (ENSIACET) ; Institut National Polytechnique (Toulouse) (Toulouse INP) ; Université de Toulouse (UT)-Université de Toulouse (UT)-Institut National Polytechnique (Toulouse) (Toulouse INP) ; Université de Toulouse (UT)-Université de Toulouse (UT) | Origine, structure et évolution de la biodiversité (OSEB) ; Muséum national d'Histoire naturelle (MNHN)-Centre National de la Recherche Scientifique (CNRS) | FUB - Research Group for Environmental Monitoring (SWITZERLAND) ; FUB - Research Group for Environmental Monitoring (SWITZERLAND) | Laboratorio Integrado de Calidad Ambiental - LICA (Pamplona, Spain) ; Universidad de Navarra [Pamplona] (UNAV) | Biogéochimie et écologie des milieux continentaux (Bioemco) ; École normale supérieure - Paris (ENS-PSL) ; Université Paris Sciences et Lettres (PSL)-Université Paris Sciences et Lettres (PSL)-Institut de Recherche pour le Développement (IRD)-Institut National de la Recherche Agronomique (INRA)-Université Pierre et Marie Curie - Paris 6 (UPMC)-AgroParisTech-Centre National de la Recherche Scientifique (CNRS) | France by the Agence de l'Environnement et de la Maitrise de l'Energie (ADEME) ; Spain by the Foundation of the University of Navarra (FUNA) ; CAN Foundation ; Switzerland by the Federal Office for the Environment (FOEN) ;Communaute de Travail des Pyrenees/Communidad de Trabajo de los Pirineos (CTP)
International audience | Polycyclic aromatic hydrocarbon (PAH) concentrations and N, C stable isotope signatures were determined in mosses Hypnum cupressiforme Hedw. from 61 sites of 3 European regions: Île-de-France (France); Navarra (Spain); the Swiss Plateau and Basel area (Switzerland). Total PAH concentrations of 100-700 ng g-1, as well as δ13C values of -32 to -29‰ and δ15N values of -11 to -3‰ were measured. Pearson correlation tests revealed opposite trends between high molecular weight PAH (4-6 aromatic rings) content and δ13C values. Partial Least Square regressions explained the very significant correlations (r > 0.91, p < 0.001) between high molecular weight PAH concentrations by local urban land use (<10 km) and environmental factors such as elevation and pluviometry. Finally, specific correlations between heavy metal and PAH concentrations were attributed to industrial emissions in Switzerland and road traffic emissions in Spain.
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