Spent pickle liquor, as a source of ferric ion, was added to primary treatment facilities and found to be effective in removing more than 60% of the phosphorus contained in the sewage. When advanced means for more complete removal of the insolubilized phosphates are available, removals in excess of 90% are indicated. In addition, overall suspended solids removals averaged 61.5% and BOD and COD removals averaged 61.6 and 55.3 percent during a 23 month test period. Required iron dosage ranged from the theoretical minimum of 2.7 to a maximum of approximately 3.1 weights of ferrous iron per weight of phosphorus. The weight increase in sludge solids due to chemical precipitation of phosphorus was 100 lbs/million gallons/mg/liter of phosphorus in the influent. Total costs for treating a raw sewage containing 13 mg/l phosphorus are given.

Seventy million pounds of seafood wastes, mainly from crab, salmon, and shrimp fishing, containing 22.1 million pounds of COD were discharged to Kodiak Harbor, Alaska in 1970. A private firm was engaged to develop a plan to permit development of beneficial uses for the wastes while concurrently reducing the pollutional load on the harbor. The plan included collection and transportation of the waste to a central processing site on Near Island for by-product recovery. Shellfish wastes would be extracted with dilute alkali to yield a high quality protein and a chitin-calcium carbonate residue, the former to be used as pet food aditives or for industrial applications, and the latter to be exported for conversion to chitin and derived products or used in Alaska as a soil liming and fertilizer material. Fish wastes would also be extracted to yield a concentrated protein product similar to fish solubles oil and bone meal.

Hot waste pickle liquor (ferrous sulfate) as an iron source was successful in precipitating phosphorus from solution in a 115 mgd East Plant of Milwaukee's Jones Island Activated Sludge Wastewater Treatment Plant. An 85 mgd section of the plant receiving the same influent was operated as a control. The East Plant with iron addition, achieved 91.3% removals (0.70 mg/1 P effluent residual), while the control West Plant removed 83.1% (1.4 mg/1 P residual). Comparison of efficiencies of purification, pH, alkalinity, and microscopic examinations of the sludge microorganism indicated that the addition of unneutralized waste pickle liquor did not adversely affect purification processes.

The report describes process changes and waste treatment, recovery, and reuse facilities installed by Volco Brass and Copper Company, Kenilworth, New Jersey. The plant produces 75 tons of wire per day. An electrolytic system was installed to recover copper from the spent primary pickle solution and to regenerate the sulfuric acid for reuse. A hydrogen peroxide bright pickle replaced the chromate and fluoride bright pickles previously used. Copper from the bright pickle is also recovered in the electrolytic system. The electrolytic copper is reused on location in casting. An integrated copper treatment system was installed to treat bright pickle drag-out. Sludge from the integrated system is recovered for sale. Rinse water consumption was reduced from 150 gpm to 10 gpm. Former discharges of chromium, ammonium, and fluoride ions have been eliminated. Cost and operating data and effluent analyses are presented.