Recovering phosphorus (P) from waste streams takes the unique advantage in simultaneously addressing the crisis of eutrophication and the shortage of P resource. A novel calcium decorated sludge carbon (Ca-SC) was developed from dyeing industry wastewater treatment sludge by decorating calcium (Ca) to effectively adsorb phosphorus from solution. The X-ray diffraction (XRD) and Fourier transform infrared (FTIR) techniques were used to characterize the Ca-SCs, followed by isotherm and kinetic sorption experiments. A preferred design with CaCO₃ to sludge mass ratio of 1:2 was found to have a sorption capacity of 116.82 mg/g for phosphorus. This work reveals the crucial role of well-dispersed nano-rod calcium on the Ca-SC surface for the sorption of phosphorus. Moreover, the decoration of nano-rod calcium was found to further promote the uptake of phosphorus through the formation of hydroxylapatite (Ca₅(PO₄)₃(OH)). Thus, the development of decorated Ca-SC for sorption of phosphorus is very important in solving the P pollution and resource loss.

Atmospheric particulates play a vital role in the transport of potentially toxic metals, being an important exposure pathways of people to toxic elements, which is faster and can occur in a much larger scale than water, soil and biota transport. Windblown materials in abandoned tailing ponds have not been well examined. The objectives of this investigation were: to study the major physical and geochemical properties of the materials eroded by wind inside the tailing ponds, and to understand the relative contribution of different sources to its heavy metals concentration. Study area is located in Cartagena-La Union mining district (SE Spain), where metallic mining of Fe, Pb and Zn has been developed for more than 2500 years. Wind-eroded particulates were monthly collected at 3 different heights (20, 50, and 80 cm) from the ground for a period of a full year using 4 dust collectors. Four tailing samples and 4 surface soil samples from the surrounding hills were also taken. Dust, soil, and tailing samples were examined for pH, particle size distribution, electrical conductivity, calcium carbonate content, Pb, Cu, Zn, Cd, Mn, Co, Ni, Ti and Zr concentrations. The results indicated that very coarse textured, slightly saline, and almost neutral wind-eroded deposits were generated with a very high temporal variability throughout the year. They also showed that the concentration of Cd, Mn, Pb and Zn, in the dust samples is extraordinarily high (18, 1254, 1831, and 5747 mg kg−1 respectively), whereas Co, Ni, and Cu had concentrations into the range of background concentrations found in the Earth's crust (3.8, 12, and 60 mg kg−1 respectively). Besides, the concentration of both categories of heavy metals in the dust samples was higher than that in tailing and less than that of the soils. The barren surfaces of tailing ponds and also the surface soils of the surrounding area seem to be the major contributors to the dust collected. Therefore, abandoned mines as well as their tailing ponds should be rehabilitated by proper technologies and then well stabilized and/or covered by appropriate plant vegetation to control the transfer, particularly by air, of environmentally hazardous materials to other areas.

Twenty four surface sediments were gathered from the Uppanar river estuary, southern India to evaluate the trace element contamination risk in the sediments. The circulation of organic matter and calcium carbonate were controlled by algal blooms and shell fragments. Moreover, the concentrations of iron and manganese in the estuarine sediments were possibly contributed by riverine sources and geogenic processes. The geoaccumulation index, enrichment factor and contamination factor reveals that the sediments were contaminated by copper and chromium. The pollution load index recommends that the estuarine sediments have the risk of pollution. The sediment pollution index highlights that the majority of the sediments are low polluted sediments. The potential ecological risk index discloses that the Uppanar river estuary is under moderate risk. The statistical analysis reveals that the organic matter content is managed by fine fractions and the majority of the trace elements are associated with each other having similar origin.

Eighty-three surface sediments were collected to investigate the element concentration based sediment pollution and potential ecological risk status of the Pulicat lagoon, southeast coast of India. The textural characteristics, Fe and Mn concentration in the surface sediments are chiefly controlled by the confluence of riverine inputs and vicinity of the marine environment. The varied distribution of CaCO₃ concentration is due to the depth of the lagoon followed by the sand and silty sand characteristics of the substratum. The surface sediments are derived from riverine sources. Sediment Pollution Index (SPI), Potential Ecological Risk Index of the sediments suggests that they are falling under less polluted and low potential ecological risk category.

Heavy metals are a common contaminant in water supplies and pose a variety of serious health risks to nearby human populations. A promising approach to heavy metal decontamination is the sequestration of heavy metal ions in porous materials; however, current technologies involve materials which can be difficult to synthesize, are high-cost, or are themselves potentially toxic. Herein, we demonstrate that rapidly synthesized calcium carbonate (CaCO₃) microparticles can effectively remove high quantities of Pb²⁺, Cd²⁺, and Cu²⁺ ions (1869, 1320, and 1293 mg per gram of CaCO₃ microparticles, respectively) from aqueous media. The CaCO₃ microparticles were characterized with powder X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and Brunauer–Emmett–Teller (BET) N₂ sorption–desorption. It was found that the Ca²⁺ ions of the microparticles were replaced by the heavy metal ions, leading to partially recrystallized nanoparticles of new compositional phases such as cerussite (PbCO₃). The adsorption, surface dissolution/re-precipitation, and nucleation/crystal growth mechanisms were determined by investigating the Ca²⁺ released, along with the changes to particle morphology and crystal structure. Importantly, this study demonstrates that the porous CaCO₃ microparticles performed well in a system with multiple heavy metal ion species: 100% of Cu²⁺, 97.5% of Pb²⁺, and 37.0% Cd²⁺ were removed from an aqueous solution of all cations with initial individual metal concentrations of 50 mg/L and 1.5 g/L of CaCO₃ microparticles. At this concentration, the CaCO₃ microparticles significantly outperformed activated carbon. These results help to establish CaCO₃ microparticles as a promising low-cost and scalable technology for removing heavy metal ions from contaminated water. Graphical abstract ᅟ

Intercropping of arsenic (As) hyperaccumulator Pteris vittata and cash crop Morus alba could improve the As concentration in the hyperaccumulator but decrease As concentration in the intercropped crop. The effects of several amendments on the transfer of As were investigated to determine an enhancement strategy for the intercropping system of P. vittata and M. alba. Phosphorus, in the form of Ca(H₂PO₄)₂, promoted the release of As to the soil solution and apparently increased the As removal from the soil by 42% compared with the untreated variant. The addition of FeSO₄ and CaCO₃ decreased As concentration in the soil solution and the uptake of As by both plant species. The As levels in the mulberry leaves remained under the threshold limits of feedstuffs in China. Intercropping was confirmed as an applicable strategy to manage contaminated soil. Hence, under the condition that all treatments produced safe mulberry leaves, Ca(H₂PO₄)₂ was the appropriate amendment to achieve the highest As removal rate, whereas FeSO₄ could lower the risk of As to further migrate to another medium.

Cement solidification is an important pre-treatment technology for municipal solid waste incineration (MSWI) fly ash into landfill. The physicochemical properties and leaching characteristics are the foundation for assessing the long-term stability of the fly ash solidified with benchmark cement in landfills. The leaching performances of bulk components (Na, K, Ca, Cl, CO₃²⁻, and SO₄²⁻) and heavy metals (Cu, Zn, Cr, Pb, and Zn) were analyzed based on the percolation column test and pH dependent test respectively. The research showed that in the cement-solidified fly ash, Na and K were mainly in the form of soluble chloride salts and would be washed out severely at the initial leaching stage due to the weak fixation effect of cement. Moreover, a considerable amount of Ca was washed out simultaneously with Na and K, causing a temporary increase in pH value, and then Ca leaching was controlled by the solubility of minerals, mainly calcium carbonate, ettringite formed with CO₃²⁻ and SO₄²⁻. Cement solidification reduced the cumulative release of mobile Cu, Zn, Cr, Pb, and Cd contained in MSWI fly ash. In the cement-solidified fly ash, the leaching of Cu and Zn was controlled by mineral solubility under alkaline conditions, Cr was dependent on the redox conditions, and Pb was related to the complex structures formed with Si–O bonds of silicates. A further research on the long-term stability of the cement-solidified fly ash in landfills was needed.

Urban soils contain significant amounts of black carbon (BC) from biomass and fossil fuel combustion and regard to be a pool of BC. BC in urban soils has multiple effects on environmental processes in urban system, such as global climate change, air quality, and public health. Urban topsoil samples (0–10 cm) were collected from Anshan, Liaoning Province, northeast China, which is one of the most important old steel industrial bases in China. The BC in urban topsoils was extracted using the density method. Their chemical composition, morphology, molecular structure, and stable carbon isotopic composition were examined using elemental analysis, scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS), Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), X-ray diffraction (XRD), and stable carbon isotope (δ¹³C). Elemental analysis shows that carbon content in the BC of studied soils ranged from 64.5 to 78.4%, with the average more than 70%. The O/C atomic ratio of BC is on average 0.18. The BC particle displays different morphology, including porous spherical, irregular porous fragmentary, and blocky shapes. The porous spherical BC particles has atomic molar O/C ratio determined by SEM-EDS ranging from 0.04 to 0.37. XRD indicates that BC exists in mainly combining with mineral phases hematite (Fe₂O₃), kaolinite (Al₂Si₂O₅(OH)₄), quartz (SiO₂), and calcite (CaCO₃). The FTIR spectra of BC particles show major bands at approximately 3400 cm⁻¹ (O–H), 2920 cm⁻¹ (C = H), 1600 cm⁻¹ (C = C), 1230 cm⁻¹ (C = O), and 1070 cm⁻¹ (C = O). The stable carbon isotope (δ¹³C) of BC ranges from −24.48 to −23.18‰ with the average of −23.79 ± 0.39‰. The concentration of BC in the industrial area is significantly (p < 0.05) higher than that in the roadside area. The BC of industrial area is characterized by porous spherical structure, suggesting that they are mainly derived from fossil fuel combustion. Results indicated that a combination of atomic O/C ratio, porous structure, and stable carbon isotopic (δ¹³C) of BC could reflect effectively the origin of BC in urban topsoils. It could conclude that BC in Anshan urban topsoil was mainly from fossil fuel combustion.

Alkalinity generation and toxic trace metal (such as vanadium) leaching from basic oxygen furnace (BOF) steel slag particles must be properly understood and managed by pre-conditioning if beneficial reuse of slag is to be maximised. Water leaching under aerated conditions was investigated using fresh BOF slag at three different particle sizes (0.5–1.0, 2–5 and 10 × 10 × 20 mm blocks) and a 6-month pre-weathered block. There were several distinct leaching stages observed over time associated with different phases controlling the solution chemistry: (1) free-lime (CaO) dissolution (days 0–2); (2) dicalcium silicate (Ca₂SiO₄) dissolution (days 2–14) and (3) Ca–Si–H and CaCO₃ formation and subsequent dissolution (days 14–73). Experiments with the smallest size fraction resulted in the highest Ca, Si and V concentrations, highlighting the role of surface area in controlling initial leaching. After ~2 weeks, the solution Ca/Si ratio (0.7–0.9) evolved to equal those found within a Ca–Si–H phase that replaced dicalcium silicate and free-lime phases in a 30- to 150-μm altered surface region. V release was a two-stage process; initially, V was released by dicalcium silicate dissolution, but V also isomorphically substituted for Si into the neo-formed Ca–Si–H in the alteration zone. Therefore, on longer timescales, the release of V to solution was primarily controlled by considerably slower Ca–Si–H dissolution rates, which decreased the rate of V release by an order of magnitude. Overall, the results indicate that the BOF slag leaching mechanism evolves from a situation initially dominated by rapid hydration and dissolution of primary dicalcium silicate/free-lime phases, to a slow diffusion limited process controlled by the solubility of secondary Ca–Si–H and CaCO₃ phases that replace and cover more reactive primary slag phases at particle surfaces.

Agricultural land is a major sink of global organic carbon (C). Its suitable management is crucial for improving C sequestration and reducing soil CO₂ emission. Incubation experiments were performed to assess the impact of phosphate solubilizing bacterial (PSB) inoculation (inoculated and uninoculated) and soil calcification (4.78, 10, 15, and 20% crushed CaCO₃) with phosphorus (P) sources [single superphosphate (SSP), rock phosphate (RP), farm yard manure (FYM), and poultry manure (PM)] in experiment 1 and with various rates of PM (4, 8, and 12 kg ha⁻¹) in experiment 2 on cumulative soil respiration. These experiments were arranged in three factorial, complete randomize design (CRD) with three replications. Interactively, lime with P sources (at day 1 and 3) and lime with PSB (at day 1) significantly expedited soil respiration. Mainly, PSB inoculation, liming, PM fertilization, and its various rates significantly enhanced soil respiration with time over control/minimum in alkaline soil at all incubation periods. Higher CO₂ emission was detected in soil supplemented with organic P sources (PM and FYM) than mineral sources (SSP and RP). CO₂ emission was noted to increase with increasing PM content. Since liming intensified CO₂ discharge from soil, therefore addition of lime to an alkaline soil should be avoided; instead, integrated approaches must be adopted for P management in alkaline calcareous soils for climate-smart agriculture.