Nitrogen (N)-enriched leaching water may act as a source of indirect N₂O emission when it is discharged to agricultural drainage ditches. In this study, indirect N₂O emissions from an agricultural drainage ditch mainly receiving interflow water were measured using the static chamber-gas chromatography technique during 2012–2015 in the central Sichuan Basin in southwestern China. We found the drainage ditch was a source of indirect N₂O emissions contributing an inter-annual mean flux of 6.56 ± 1.12 μg N m⁻² h⁻¹ and a mean indirect N₂O emission factor (EF₅g) value of 0.03 ± 0.003%. The mean EF₅g value from literature review was 0.51%, which was higher than the default EF₅g value (0.25%) proposed by the Intergovernmental Panel on Climate Change (IPCC) in 2006. Our study demonstrated that, more in situ observations of N₂O emissions as regards N leaching are required, to account for the large variation in EF₅g values and to improve the accuracy and confidence of the default EF₅g value. Indirect N₂O emissions varied with season, higher emissions occurred in summer and autumn. These seasonal variations were related to drainage water NO₃⁻-N concentration, temperature, and precipitation. Our results showed that intensive precipitation increased NO₃⁻-N concentrations and N₂O emissions, and when combined with warmer water temperatures, these may have increased the denitrification rate that led to the higher summer and autumn N₂O emissions in the studied agricultural drainage ditch.

This study evaluated the PAH bioavailability from Santos Bay (Brazil) in 4 species of fish, using PAH biliary metabolites. The collection was done monthly, between July and December, in three different regions of Santos Bay. The metabolites were analyzed through a high performance liquid chromatograph with fluorescence detectors. Total metabolites concentrations ranged from 65.5 to 589μgg−1 of bile, evidencing PAH bioavailability on Santos Bay. Levels of phenanthrene and benzo[a]pyrene metabolites were in the classification range of areas moderate contaminated. Those concentrations were lower in Nebris microps and higher in Sphoeroides testudineus (p<0.05). Naphthalene metabolites concentrations did not differ significantly among fish species and were in the classification range of low contaminated areas. There were no significant spatial and temporal differences in levels among sampled areas. These results are environmentally important given the high levels of urbanization and the absence of biomonitoring data in this area.

Tar balls are prevalent in oceans and the coastal environment; however, their origins are not well constrained on a global scale. To address this, we used gas chromatography to analyze the molecular composition of a unique set of 100 pelagic tar balls collected in the Western North Atlantic and Caribbean Sea between 1988 and 2016. Hierarchal cluster analysis (HCA) was employed to classify the samples into groups based on the relative proportions of resolved and unresolved hydrocarbon distributions. Additional analysis of polycyclic aromatic hydrocarbons revealed that 28% of samples originated from heavy fuel oils and therefore had anthropogenic origins consistent with the classifications based on HCA. Other samples examined could originate from anthropogenic or natural origins, such as natural seeps. This study provides a preliminary record of 100 classified pelagic tar ball samples and demonstrates an approach to determine their origin to the environment.

Chemicals such as polycyclic aromatic hydrocarbons (PAHs), phthalateesters, parabens, siloxanes and squalene, all of them classified as endocrine-disrupting chemicals (EDCs), have been reported to occur in all environmental compartments. The effects of EDCs on development, reproduction, growth, metabolism and obesity constitute a real public health issue. A list of EDCs (> 40 compounds) were characterised in total suspended particulates (outdoor soot: 92 samples) collected in July–September 2016 in an Algiers urban area; besides, settled indoor dusts (36 samples) were collected between November and December 2016 in schools, homes, manufacture and hospital of the same province. The analytical procedure consisted of ultrasonic bath extraction, column chromatography separation into fractions of different polarity and gas chromatographic-mass spectrometric processing. The total loads of phthalates ranging from 6.0 to 347 ng/m² (median, 26 ng/m²) were determined in indoor dust and 4.6 to 11.6 ng/m³ (median, 7.9 ng/m³) in outdoor soot; meanwhile, PAHs ranged from 12.1 to 108 ng/m² (median, 36 ng/m²) in indoor dust and ranged from 5.6 to 7.7 ng/m³ (median 5.7 ng/m³) in outdoor soot. Finally, illicit substances such as cocaine, cannabinol and Δ⁹-tetrahydrocannabinol were found to range from 0.5 to 11 pg/m³, 4.6 to 9.2 pg/m³ and 11 to 81 pg/m³, respectively, in outdoor soot.

Inorganic anion monitoring is essential for bioreactor operation and is related for pollution control or energy and products recovery. However, there is a lack of studies validating methods for inorganic anions analyses in conditions compatible to those in bioreactor operations treating different types of wastewater. This paper provides a systematic statistical study and matrix-effect assessment for sugarcane vinasse, leachate, sewage and synthetic sewage. Sample preparation consisted of only a filtration and sample dilution. Cl⁻, NO₂⁻, NO₃⁻, PO₄³⁻ and SO₄²⁻ were determined in a Dionex ICS 5000® equipped with a chemical conductivity suppressor. Calibration curves were linear and well-adjusted between 2.5 and 50 mg L⁻¹ for all the anions in all the tested matrices, except PO₄³⁻ and SO₄²⁻ in vinasse. A calibration range for PO₄³⁻ in all tested matrices was 5.0 to 100 mg L⁻¹, whereas a range from 5.0 mg L⁻¹ to 50 mg L⁻¹ was obtained for SO₄²⁻ in vinasse. All the anions yielded recoveries in the range of 85–115% for all the tested matrices. Relative standard deviations lower than 10 and 2% were achieved for peak areas and retention times, respectively. A signal enhancement was observed for all the tested matrices and all the anions. The matrix effect level varied from −1.7 (NO₂⁻ in vinasse) to −33.9% (Cl⁻ in leachate). Sewage was the less affected matrix, while leachate gave higher matrix effects. Validation results and the matrix effect assessment showed that a simple sample preparation is suitable for multi-elemental analyses of inorganic anions for complex environmental samples.

The Subaé river watershed is considered one of the most critical Pb-impacted environments in Brazil and around the world, due to pollutant dispersion during 33 years of lead ore purification in Santo Amaro da Purification. Severe damages have been reported in biota and population, which depends on the Subaé river watershed quality for agriculture, fishing, and shellfish harvesting. This study aims to understand the geochemical characteristics and dynamics of the river close to the former Pb smelter. The river was sampled at eight sites upstream and eight sites downstream the smelter, near the estuary in the Todos os Santos Bay, six times during a year. Immediate analyses were performed by multiprobe. Major ions were measured by chromatography, dissolved metals by ICP-OES in the filtrated samples (0.45 μm), and particulate metals > 0.45 μm by EDX spectrometry. The ions Na⁺ and HCO₃⁻ are dominated in the river. Most of the samples (47.6%) were classified as sodic, due to oceanic saline intrusion during tide. Despite the high pollution caused by the smelter from 1960 to 1993, still observed in the surrounding soils, dissolved and particulate metals in the river remained low in all sites during the entire year. Only Cu presented some concentration above the threshold of the Brazilian regulations. The discharge of metals by the river into the Todos os Santos Bay appears to be low for Pb and Zn (2.2 and 14.3 kg km⁻¹ year⁻¹, respectively), but higher for Cu comparatively to other worldwide bays.

The presence of various classes of pharmaceutical drugs in different environmental compartments has been reported worldwide. In South Africa, the detection of pharmaceuticals especially the non-steroidal anti-inflammatory drugs is recent, and more studies are being done in order to fully understand their fate in the aquatic environment. With considerations for the need of better sample preparation techniques, this study synthesized a molecularly imprinted polymer for the selective extraction of a non-steroidal anti-inflammatory drug, fenoprofen in aqueous environmental samples. Batch adsorption studies showed that adsorption of fenoprofen onto the cavities of the polymer followed a Langmuir isotherm as well as a pseudo second order model implying formation of a monolayer on the surface through chemisorption. The polymer had a maximum adsorption capacity of 38.8 mg g⁻¹ and a Langmuir surface area of 1607 m² g⁻¹. The imprinted polymer was then used as the selective sorbent for solid phase extraction in the analysis of fenoprofen from wastewater followed by chromatographic determination. The analytical method gave a detection limit of 0.64 ng mL⁻¹ and recovery of 99.6%. The concentration of fenoprofen detected in influent and effluent samples from two wastewater treatment plants ranged from 24 to 58 ng mL⁻¹. The ability of the treatment plants to remove fenoprofen during wastewater processing based on the difference in concentrations in influent and effluent samples was found to be 41%. This work has shown that there is a possibility of release of fenoprofen from wastewater treatment plants into surface water sources.