Soil fumigation continues to play an important role in soil disinfection, but tools to significantly reduce emissions while providing environmental benefits (e.g., biochar) are lacking. The objective of this study was to determine the effects of biochar products on fumigant 1,3-dichloropropene (1,3-D) and chloropicrin (CP) emissions, their distribution and persistence in soil, nematode control, and potential toxicity to plants in a field trial. Treatments included three biochar products [two derived from almond shells (ASB) at either 550 or 900 °C pyrolysis temperature and one from coconut shells (CSB) at 550 °C] at 30 and 60 t ha⁻¹, a surface covering with a low permeability film (TIF), and no surface covering (control). A mixture of 1,3-D (∼65%) and CP (∼35%) was injected to ∼60 cm soil depth at a combined rate of 640 kg ha⁻¹. All biochar treatments significantly reduced emissions by 38–100% compared to the control. The ASB (900 °C) at both rates reduced emissions as effectively as the TIF (by 99–100%). Both fumigant emission reduction and residue in surface soil were positively correlated with biochar's adsorption capacity while cucumber germination rate and dry biomass were negatively correlated with residual fumigant concentrations in surface soil. This research demonstrated the potential and benefits of using biochar produced from local orchard feedstocks to control fumigant emissions. Additional research is needed to maximize the benefits of biochar on fumigant emission reductions without impacting plant growth.

The purpose of this study was to investigate antibiotic resistant fungal (ARF) communities in pig manure (PM) composting employing two different biochar (coconut shell-CSB and bamboo biochar-BB) as amendment. Three treatments (Control, 10% CSB and 10% BB) were designed and indicated with T1 to T3. Experimental results declared that the fungal abundance significantly reduced among the both biochar applied treatments but three dominant phyla Ascomycota, Basidiomycota and Mucoromycota were still relatively greater abundance present. There were significant differences (p < 0.05) in the relative abundance and diversity of fungi among all three treatments. Interestingly, biochar addition regulated the overall fungal community in final compost. Compared with the control group, the abundance of fungi was positively mobilized, and especially CSB showed a better effect. Conclusively, biochar has potential to inhibit and reduce the ARGs population and mobility in compost. Thus, these findings offer new insight to understand the succession of ARFs during PM composting.

This paper for the first time synthesizes novel biodiesel experimentally using low-cost feedstocks of coconut oil, caustic soda, and fermented palm wine contaminated by microorganisms. The alkaline catalyzed transesterification method was used for biodiesel production with minimal glycerol. The produced biodiesel was biodegradable and effective in cleaning a shoreline oil spill experiment verified by our developed oil spill radial numerical simulator. For the first time, an adaptive neuro-fuzzy inference system (ANFIS) was hybridized with invasive weed optimization (IWO), imperialist competitive algorithm (ICA), and shuffled complex evolution (SCE-UA) to predict biodiesel yield (BY) using obtained Monte Carlo simulation datasets from the biodiesel experimental seed data. The test results indicated ANFIS-IWO (MSE = 0.0628) as the best model and also when compared to the benchmarked ANFIS genetic algorithm (MSE = 0.0639). Additionally, ANFIS-IWO (RMSE = 0.54705) was tested on another coconut biodiesel data in the literature and it outperformed both response surface methodology (RMSE = 0.72739) and artificial neural network (RMSE = 0.68615) models used. The hybridized models proved to be robust for biodiesel yield modeling in addition to the produced biodiesel serving as an environmentally acceptable and cost-effective alternative for shoreline bioremediation.

The worldwide resurgence of natural dyes in all fields is due to the carcinogenic effects of effluent loads shed by synthetic industries. Coconut coir (Cocos nucifera) containing tannin as a source of natural colorants has been selected for coloration of bio-mordanted silk under the influence of ultrasonic radiations at various dyeing conditions. For extraction of tannin dye from cocos powder, different media were employed, and dyeing variables such as dyeing time, dye bath pH, dyeing bath temperature, and the effect of salts on dyeing were optimized. For achieving new shades with excellent color characteristics, bio-mordants in comparison with chemical mordants were employed. It has been found that acid-solubilized extract after ultrasonic treatment for 45 min has yielded high color strength, when coconut coir extract of 4 pH from 6g of cocos powder, containing 5g/100mL salt solution as exhaust agent, was used to dye silk at 75°C for 65 min. Among bio-mordants turmeric (K/S=13.828) and among chemical mordants iron has shown excellent results (K/S=2.0856). Physiochemical analysis of fabric before and after US treatment shows that there is no change in the chemical structure of the fabric. It is found that ultrasonic waves have excellent potential to isolate the colorant followed by dyeing and environmental friendly mordanting at optimal conditions, but also the usage of herbal-based plant anchors, i.e., bio-mordants, has made the natural dyeing process more sustainable and clean.

Demand for particleboards keeps increasing and as such more trees are fell for its production, engendering deforestation. For the purpose of reducing falling of trees, this study, focused on recycling of waste paper in the development of paperboard as alternative to particleboards used for furniture and interior household applications. Kenaf fiber (KF) was blended at varying proportions of 0, 1, 2, 3, 4, and 5 wt.% with 20 wt.% constant cement and 20 wt.% constant coconut shell powder while the remaining was paper pulp. Board specimen developed were cured for 14, 28, and 90 days and mechanical properties were examined. Results obtained showed that fiber dosage improved bond strength and screw holding strengths as compared with the control mix. Similarly, modulus of rupture was enhanced with KF loading as compared with control mix while 1 to 3 wt.% KF spawned enhancement of modulus of elasticity. However, 4 and 5 wt.% KF led to a reduction in the modulus. Infusion of the fiber enhanced tensile strength from 1 to 3 wt.% content. 14-day and 28-day curing periods were observed to improve properties while the 90-day curing period is detrimental to all properties. Optimization via signal-to-noise ratio revealed an optimum mix of 2 wt.% obtained for fiber and an optimum curing duration of 28 days.

Concrete is one of the most important materials that are used in the construction industry all around the world. A larger part of the capacity in concrete is generally employed by the coarse aggregate. Due to the tremendous use of coarse aggregate in the construction industry, the material is getting degraded. In order to preserve the natural material, we are in search of an alternate material that can be used in concrete instead of the original one. So in this research work, it has been attempted to study the mechanical behaviour of lightweight concrete when we use waste coconut shell as coarse aggregate inside concrete. To improve the strength of the concrete, we also use the sisal fibres in various proportions ranging between 1 and 5% in accordance to the binder weight. After the mechanical property tests such as the compression test, spilt tensile strength, flexural test, modulus of elasticity test, and impact resistant test were conducted, finally it was concluded that there was increment in the compression strength up to 5%, and tensile strength was increased to 17% and elastic modulus to 7% when the fibre content used was 3%. Thus, with the use of these waste materials, it was found that the concrete’s strength gets increased and it leads to the formation of sustainable concrete thus reducing the pollution in the environment.

Hexazinone, a globally applied broad-spectrum triazine herbicide, has not been mechanistically investigated previously under advanced oxidation processes (AOPs) and adsorption on activated carbon. In this study, its fate during UV-based oxidation with/without hydrogen peroxide (H₂O₂) and adsorption on coconut shell–based granular activated carbon (CSGAC) in water matrices was investigated. A comparison between various irradiation sources (visible, UVA, UVB, and UVC) revealed the highest degradation rate under UVC. More than 98% degradation of hexazinone was observed under 3 J cm⁻² UVC fluence in the presence of 0.5 mM H₂O₂ at pH 7. Moreover, the degradation rate enhanced significantly with an increase in the initial dosage of H₂O₂, UV fluence, and contact time in the UV/H₂O₂ process. The rate of degradation was lower using secondary effluent than that of Milli-Q water due to the presence of dissolved organics in wastewater. However, the reactions in both matrices obeyed pseudo-first-order kinetics. The effect of different scavengers, including methanol, potassium iodide (KI), and tert-butyl alcohol (TBA), showed that hydroxyl radicals (•OH) played a dominant role in hexazinone degradation in the UV/H₂O₂ process. Hexazinone was effectively adsorbed by CSGAC through π-π electron donor–acceptor interactions between hexazinone’s triazine ring and CSGAC’s surface functional groups. The isotherm and kinetic studies showed that the adsorption followed the Freundlich model and pseudo-second-order reaction, respectively, suggesting chemisorption. This study provided mechanistic insights on the removal of hexazinone at the tertiary stage of wastewater treatment or the advanced treatment of wastewater reuse.

The quest for eco-sustainable binders like agro-wastes in concrete to reduce the carbon footprint caused by cement production has been ongoing among researchers recently. The application of agro-waste-based cementitious materials in binary concrete has been said to improve concrete performance lately. Coconut and groundnut shells are available in abundant quantities and disposed of as waste in many world regions. Therefore, the use of coconut shell ash (CSA) and groundnut shell ash (GSA) in a ternary blend provides synergistic benefits with Portland cement (PC) and may be sustainably utilized in concrete as ternary cementitious material (TCM). Therefore, this study presents concrete performance with CSA and GSA in a grade 30 ternary concrete. Two hundred ten numbers of standard concrete samples were cast for checking the fresh and mechanical properties of concrete at curing ages of 7, 28, and 90 days. After 28-day curing, the experimental results show an increment in compressive, tensile, and flexural strength by 11.62%, 8.39%, and 9.46% at 10% TCM cement replacement, respectively. The concrete density and permeability coefficient reduce as TCM’s content increases. The modulus of elasticity after 90 days improved with the addition of TCM. The concrete’s sustainability assessment indicated that the emitted carbon for concrete decreased by around 16% using 20% TCM in concrete. However, the workability of fresh concrete declines as TCM content increases.

A new adsorbent from Jerivá coconut (a fruit native to the Atlantic Forest) was developed through thermal and chemical activation with H₃PO₄. The characterization of activated carbon using SEM–EDS revealed an irregular and heterogeneous surface, with a surface area of 750 m² g⁻¹, while FTIR indicated the presence of functional groups. The adsorption kinetics was favorable, reaching equilibrium in 80 min, removing more than 99% of the initial concentration (100 mg L⁻¹) of methylene blue; the Avrami model had a better fit to the data. The sorption isotherms performed at four temperatures showed endothermic behavior, with a maximum adsorption capacity of 254.40 mg g⁻¹, with adjustment to the Sips model. The mechanisms involved in dye adsorption were discussed and elucidated. The adsorbent was tested to remove the color of the real effluent from the textile industry, and the results showed discoloration superior to 93%, meeting international disposal limits. The results confirm the efficiency of the new adsorbent and the possibility of application in the treatment of textile effluents.

The drying of food products is an essential step in the preservation of crops and agricultural by-products that serve as raw materials for numerous end applications. Solar drying with phase change materials (PCMs) is an efficient low-energy consumption process in the post-reaping stage, reducing food deterioration. A customized solar dryer setup was assembled using Cudappah (black) stones as the base of the drying chamber to facilitate the absorption of solar energy on its surface. The organic paraffin wax, with a melting point of 60 ℃, was used as PCM in the solar dryer. The novelty of the study is the application of a PCM in a solar dryer to improve the effectiveness of drying and decrease the absolute drying period and the microbial content in the dried coconut. The study compared the drying characteristics between open sun drying and solar drying without and with PCM (100 and 200 g). The fabricated setup was utilised for drying coconut using a PCM-based solar drying method. The coconut was dried from an initial moisture content of 55.5% to a final moisture content of about 9%. The prototype dryer model minimized the use of the workforce, avoided improper drying, and decreased the absolute drying time. A total plate count (TPC) test was conducted to characterize the microbial content in the dried coconut. The microbial count decreased with the use of 200-g PCM as the use of PCM retained the heat for a longer time in the chamber. The drying time of coconut decreased by about 28 and 52 h on using 100 and 200 g of PCM, respectively, compared to open sun drying. The sensory characteristics like colour, taste, flavour, quality, and texture of the solar-dried coconut sample were superior to the sun-dried coconut sample.