Surface ozone (Surface O3)is a secondary pollutant and there are only limited studies on ozone in South India. Studies have revealed a strong correlation between higher ozone levels and warmer days. Surface O3 along with its precursors like NO2, CO and CH4 are being measured at Kanyakumari (8.0780° N, 77.5410° E), TamilNadu, India and in this paper we present the summer time variation of ozone from 2010to 2014 . Surface O3 showed a clear diurnal variation, but an irregularity was observed during the night time for all the measuring days of Summer 2014.There was a formation of a well pronounced secondary peak in Surface O3 during 0230 hrs accompanied by relatively strong wind patterns. Since the normal diurnal variation cannot explain this phenomenon,this uncertain behavior is probably attributed tolow NOX titrations and the downward mixing of ozone in the ground layer.The daily mean of Surface O3showed an increasing trend in the study area during the summer monthsand a negative correlation was observed with its precursors. The correlation of Surface O3 with temperature and wind speed for the entire summer season was found as r= +0.68, p= 4.314E-05 and r= +0.63, p