Radon is a natural radioactive gas present in the environment, which is considered as the second most important lung cancer cause worldwide. Currently, radon gas is under focus and was classified as contaminant of emerging concern, which is responsible for serious biological/health effects in human. In presented work we propose the numerical model and analysis method for radon diffusion rate measurements and radon transport parameters determination. The experimental setup for radon diffusion was built in a classical, two chamber configuration, in which the radon source and outlet reservoirs are separated by the sample being tested. The main difference with previously known systems is utilization of only one radon detector, what was achieved by a careful characterization of the Rn-222 source and development of a numerical model, which allows for exact determination of radon transport parameters by fitting simulated radon concentration profile in the outlet reservoir to experimental data. For verification of the developed system, several insulation materials commonly used in building industry and civil engineering, as well as, common building materials (gypsum, hardened cement paste, concrete) were tested for radon diffusion rate through these barriers. The results of radon transmittance, permeability and diffusion coefficients for investigated materials are in compliance with values known previously from the literature. The analysis method is fast and efficient, and requires measurement period varying from a dozen or so hours up to 2–3 days depending on material properties. The described method is entirely based on a numerical analysis of the proposed differential equation model using freely available SCILAB software and experimental data obtained during sample measurements.

Here we estimate the importance of vertical eddy diffusion in removing perfluorooctanoic acid (PFOA) from the surface Ocean and assess its importance as a global sink. Measured water column profiles of PFOA were reproduced by assuming that vertical eddy diffusion in a 3-layer ocean model is the sole cause for the transport of PFOA to depth. The global oceanic sink due to eddy diffusion for PFOA is high, with accumulated removal fluxes over the last 40 years of 660 t, with the Atlantic Ocean accounting for 70% of the global oceanic sink. The global oceans have removed 13% of all PFOA produced to a depth greater than 100 m via vertical eddy diffusion; an additional 4% has been removed via deep water formation. The top 100 m of the surface oceans store another 21% of all PFOA produced (∼1100 t).

Contaminated sediments in the St. Lawrence River remain a difficult problem despite decreases in emissions. Here, sediment and pore water phases were analyzed for total mercury (THg) and methyl mercury (MeHg) and diffusion from the sediment to the overlying water was 17.5 ± 10.6 SE ng cm−2 yr−1 for THg and 3.8 ± 1.7 SE ng cm−2 yr−1 for MeHg. These fluxes were very small when compared to the particle-bound mercury flux accumulating in the sediment (183 ± 30 SE ng cm−2 yr−1). Studies have reported that fish from the westernmost site have higher Hg concentrations than fish collected from the other two sites of the Cornwall Area of Concern, which could not be explained by differences in the Hg flux or THg concentrations in sediments, but the highest concentrations of sediment MeHg, and the greatest proportions of MeHg to THg in both sediment and pore water were observed where fish had highest MeHg concentrations.

The contribution of ZAMG to MONAROP consists of special weather forecasts to control the SOCs sampling procedure and of the analysis of the specific transport processes for SOCs, which is still in progress. In this paper, air pollutant transport into the Alps is demonstrated by examples of inorganic pollutants: Measurements of NOx and ozone provide evidence for air pollutant transport by local wind systems (valley and slope winds), especially at low elevated sites of the Alps. In addition, trajectory analyses for the high elevation sites demonstrate the importance of large scale synoptic air pollutant transport. The effects of these transport processes with different spatial and temporal scales are governed by the physical and chemical properties of the particular pollutant. First results for the high alpine MONARPOP stations show that air masses from east Europe influence mostly Sonnblick (Austria), whereas the influence of the Po basin is strongest at Weissfluhjoch (Switzerland). Effects of meteorological transport processes on air pollution in the Alps are demonstrated by examples of inorganic pollutants and first conclusions for SOCs are drawn.

An integrative passive sampler consisting of a C18 Empore® disk receiving phase saturated with n-octanol and fitted with low-density polyethylene diffusion membrane was calibrated for the measurement of time-weighted average concentrations of hydrophobic micropollutants, including polyaromatic hydrocarbons and organochlorine pesticides, in water. The effect of temperature and water turbulence on kinetic and thermodynamic parameters characterising the exchange of analytes between the sampler and water was studied in a flow-through system under controlled conditions. It was found that the absorption of test analytes from water to the sampler is related to their desorption to water. This allows for the in situ calibration of the uptake of pollutants using offload kinetics of performance reference compounds. The sampling kinetics are dependent on temperature, and for most of the tested analytes also on the flow velocity. Sampler–water partition coefficients did not significantly change with temperature.

Organophosphates (OPEs) are manmade organic pollutants that are widely used as flame retardants, plasticizers, and antifoaming and hydraulic agents. In this study, seven OPEs in seawater and sediment from the Yellow Sea and East China Sea were determined to study the distribution and diffusion behavior, and to evaluate the environmental risks. The ΣOPEs in the seawater and sediments ranged from below the method detection limit (<MDL) to 497.40 ng/L and from < MDL to 66.50 ng/g dw, respectively. Tri-n-butyl phosphate (TnBP), tris-(1, 3-Dichloro-2-Propyl) phosphate (TDCPP), and tri-meta-cresyl phosphate (TmCP) were the dominant OPEs in the seawater and sediments. OPEs were mainly distributed in coastal areas and the South Yellow Sea, indicating that they are mainly affected by land-based pollution and ocean currents. Fugacity analysis shows that tri-para-cresyl phosphate (TpCP) was in a state of equilibrium, while TDCPP, TnBP, and TmCP other OPEs tended to diffuse from sediment to water. The diffusion behavior of OPEs is mainly affected by their chemical properties. Hazard quotient (HQ) values of TmCP and TpCP in sediment samples were >1.0, indicating high ecological risks to aquatic organisms.

Brominated flame retardants (BFRs) are an important group of additives in plastics that increase resistance to ignition and slow down the rate of burning. Because of concerns about their environmental and human health impacts, however, some of the most widely employed BFRs, including hexabromocyclododecane (HBCD) and commercial mixtures of penta-, octa- and deca- (poly)bromodiphenyl ethers (PBDEs), have been restricted or phased out. In this review, the oceanic sources and pathways of PBDEs, the most widely used BFRs, are evaluated and quantified, with particular focus on emissions due to migration from plastics into the atmosphere versus emissions associated with the input of retarded or contaminated plastics themselves. Calculations based on available measurements of PBDEs in the environment suggest that 3.5 and 135 tonnes of PBDEs are annually deposited in the ocean when scavenged by aerosols and through air-water gas exchange, respectively, with rivers contributing a further ∼40 tonnes. Calculations based on PBDE migration from plastic products in use or awaiting or undergoing disposal yield similar net inputs to the ocean but indicate a relatively rapid decline over the next two decades in association with the reduction in the production and recycling of these chemicals. Estimates associated with the input of PBDEs to the ocean when “bound” to marine plastics and microplastics range from about 360 to 950 tonnes per year based on the annual production of plastics and PBDEs over the past decade, and from about 20 to 50 tonnes per annum based on the abundance and distribution of PBDEs in marine plastic litter. Because of the persistence and pervasiveness of plastics in the ocean and diffusion coefficients for PBDEs on the order of 10⁻²⁰ to 10⁻²⁷ m² s⁻¹, microplastics are likely to act as a long-term source of these chemicals though gradual migration. Locally, however, and more important from an ecotoxicological perspective, PBDE migration may be significantly enhanced when physically and chemically weathered microplastics are exposed to the oily digestive fluids conditions of fish and seabirds.

Given that studies on actual sewage treatment plants are often affected by environmental conditions, it is challenging to clearly understand the associated bioaerosol generation and diffusion characteristics during the aeration process. Therefore, to enhance understanding in this regard, in this study, bioaerosol generator was used to simulate bioaerosol generation and diffusion under two aeration modes, i.e., bubble bottom aeration and brush surface aeration. The total concentration range of culturable bacteria in the bioaerosol produced by bubble bottom aeration and that produced by brush surface aeration were 300–3000 CFU/m³. Under bubble bottom aeration, the generated bioaerosol was symmetrically distributed around the source point, whereas under brush surface aeration, it was primarily distributed in the forward direction of the rotating brush surface. These bioaerosols from bubble bottom aeration predominantly consisted of particles with sizes below 3.3 μm, particularly those with sizes in the range 1.1–2.1 μm. On the contrary, the bioaerosols produced via brush surface aeration predominantly consisted of particles with sizes above 3.3 μm. The distribution characteristics of population structure in the two aeration modes were consistent with the distribution characteristics of concentration in the corresponding models. Additionally, the results showed that when the aeration process is unaffected by environmental conditions (particle matters, wind direct, wind speed, etc.), the bioaerosol components originate primarily from the parent sewage or sludge, and do not diffuse far from the source point. Therefore, source reduction (capping or sealing) can be recommended as the primary control strategy for bioaerosols in sewage treatment plants. The adoption of such measures will significantly limit the diffusion of bioaerosols, thereby reducing the potential risks associated with human exposure.

Five cement- and five lime-based building materials were examined in an environmental chamber for their emissions of Volatile Organic Compounds (VOCs). Typical VOCs were below detection limits, whereas not routinely analysed VOCs, like neopentyl glycol (NPG), dominated the cement-based products emissions, where, after 72 h, it was found to occur, in levels as high as 1400 μg m⁻³, accounting for up to 93% of total VOCs. The concentrations of NPG were not considerably changed between the 24 and 72 h of sampling. The permeability of building materials was assessed through experiments with a dual environmental chamber; it was shown that building materials facilitate the diffusion of chemicals through their pores, reaching equilibrium relatively fast (6 h).

A dynamic fugacity model was developed to simulate the spatial and seasonal variations of PAHs in Haihe Plain, China. The calculated and measured concentrations exhibited good consistency in magnitude with deviations within a factor of 4 in air and 2 in soil. The spatial distributions of PAHs in air were mainly controlled by emission while the seasonal variations were dominated by emission and gas–particle partition. In soil, the spatial distributions of PAHs were controlled by the soil organic carbon content while the seasonal variations were insignificant. The severest soil contamination was observed in Shanxi and followed by the southwest of Hebei province. Transfer fluxes of total PAHs between air and soil were calculated. The spatial distribution of air-to-soil flux was closely related to the landcover while the soil-to-air flux changed with soil organic matter content. Monte Carlo simulation was done to evaluate the uncertainty of the estimated results in air.