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A facile approach for rapid on-site screening of nicotine in natural tobacco
2020
Yu, Chaofan | Yu, Jie | Zhang, Huirong | He, Ziyan | Sha, Yunfei | Liu, Baizhan | Wang, Ying
Nicotine (Nic) exposed to the environment which comes from tobacco products is the main addictive agent and specific classes of hazardous compound that merit concern. In this study, we have established a fast and reliable method to achieve specific detection of Nic in natural nicotiana tabacum within 30 s through a miniaturized platform based on screen printed gold electrode (SPE). A simple electrochemical pretreatment mean was employed on gold surface that led to the exposure of Au (111) facet and a convenient sample pretreatment method was adopted to realize the extraction of Nic in tobacco. The present electrochemical sensor exhibits an ample range of sensing from 10 μg/g to 200 μg/g, which is able to compliance with tobacco industry testing standards of actual samples. Over 60 sampling points from different origins in China or other countries were performed with direct analysis using this method and satisfactory results have been obtained. The proposed approach was demonstrated to be a very promising platform for significantly improving analytical efficiency in laboratories as well as for monitoring the source reduction control of Nic in the environment.
Show more [+] Less [-]Application of Ti/IrO2 electrode in the electrochemical oxidation of the TNT red water
2020
Jiang, Nan | Wang, Yuchao | Zhao, Quanlin | Ye, Zhengfang
Via the thermal sintering, a nanocrystalline IrO₂ coating was formed on the Ti substrate to successfully prepare a Ti/IrO₂ electrode. Based on the electrochemical analysis, the prepared Ti/IrO₂ electrode was found to have powerful oxidation effect on the organics in the TNT red water, where the nitro compound was oxidized through an irreversible electrochemical process at 0.6 V vs. SCE. According to the analysis of the nitro compound content, the UV–vis spectra, and the FTIR spectra of 2,4,6-trinitrotoluene (TNT) red water with electrolytic periods, the degradation mechanism of the dinitrotoluene sulfonate (DNTS) was developed. And the intermediates were characterized by UPLC-HRMS. The DNTS mainly occurred one electron transfer reaction on the Ti/IrO₂ electrode. At the early stage of the electrolysis, the polymerization of DNTS was mainly dominated. The generated polymer did not form a polymer film on the electrode surface, but instead it promoted a further reduction. After electrolyzing for 30 h, all NO₂ function group in the TNT red water was degraded completely.
Show more [+] Less [-]Insights into degradation pathways and toxicity changes during electro-catalytic degradation of tetracycline hydrochloride
2020
Liu, Haiyang | Qu, Jiao | Zhang, Tingting | Ren, Miao | Zhang, Zhaocheng | Cheng, Fangyuan | He, Dongyang | Zhang, Ya-nan
The removal of antibiotics has attracted much attention due to their extremely high adverse impacts on the environment. However, the potential risks of degradation intermediates are seldom reported. In this work, the influence of different factors on the electro-catalytic degradation efficiency of tetracycline hydrochloride (TCH) by the prepared carbon nanotubes/agarose/indium tin oxide (CNTs/AG/ITO) electrode was investigated. Under optimal conditions (10 wt% CNTs dosage, pH = 7), the maximum degradation efficiency for TCH (10 mg L⁻¹) reached up to 96% within 30 min treatment with 4 V potential. Superoxide anions (•O₂⁻) played an important role in the electro-catalytic degradation. Totally 10 degradation intermediates were identified using HPLC-MS/MS, and the degradation pathway was proposed. Toxicities of the parent antibiotic and the identified intermediates were calculated using the ECOSAR (Ecological Structure Activity Relationship) program in EPISuite, and results showed that more toxic intermediates were generated. The maximal chronic toxicity for green algae of the intermediate increased 1439.92 times. Furthermore, antimicrobial activity was further verified by disk agar biocidal tests with Escherichia coli ATCC25922 and higher biotoxicity intermediates compared with parent compounds were confirmed to be formed. Therefore, more attention should be paid on the potential risk of degradation intermediates in the treatment of wastewater containing antibiotics.
Show more [+] Less [-]Associations of fluoride exposure with sex steroid hormones among U.S. children and adolescents, NHANES 2013–2016
2020
Bai, Rongpan | Huang, Yun | Wang, Fang | Guo, Jing
Fluoride mediated disruption of sex steroid hormones has been demonstrated in animals. However, evidence from humans was limited and contradictory, especially for children and adolescents. Based on data of the National Health and Nutrition Survey (NHANES) 2013–2016, a total of 3392 subjects aged 6–19 years were analyzed in this cross-sectional study. Both plasma and water fluoride levels were quantified electrometrically using the ion-specific electrode. Sex steroid hormones of total testosterone, estradiol and sex hormone-binding globulin (SHBG) were tested in serum. Percent changes and 95% confidence intervals (CIs) in sex steroid hormones associated with tertiles of fluoride levels (setting the first as reference) were estimated using adjusted linear regression models by stratification of gender and age. Compared with subjects at the first tertile of plasma fluoride, percent changes (95% CIs) in testosterone were −8.08% (−17.36%, 2.25%) and −21.65% (−30.44%, −11.75%) for the second and third tertiles, respectively (P ₜᵣₑₙd <0.001). Male adolescents at the third tertile of plasma fluoride had decreased levels of testosterone (percent change = −21.09%, 95% CIs = −36.61% to −1.77%). Similar inverse associations were also found when investigating the relationships between plasma fluoride and estradiol. Besides, the data indicated decreased levels of SHBG associated with water and plasma fluoride among the male adolescents (percent change of the third tertile = −9.39%, 95% CIs = −17.25% to −0.78%) and female children (percent change of the second tertile = −10.78%, 95% CIs = −17.55% to −3.45%), respectively. The data indicated gender- and age-specific inverse associations of fluoride in plasma and water with sex steroid hormones of total testosterone, estradiol and SHBG in U.S. children and adolescents. Prospective cohort studies are warranted to confirm the causality.
Show more [+] Less [-]Electrochemical removal of levofloxacin using conductive graphene/polyurethane particle electrodes in a three-dimensional reactor
2020
Guo, Cuicui | Liu, Haiyang | Wang, Chengzhi | Zhao, Jianchen | Zhao, Wenjun | Lu, Nan | Qu, Jiao | Yuan, Xing | Zhang, Ya-nan
The conductive polyurethane/polypyrrole/graphene (CPU/PPy/Gr) particle electrode was prepared by an in-situ oxidative polymerization method and used as particle electrodes to degrade levofloxacin (LEV) in a three-dimensional electrode reactor. The prepared CPU/PPy/Gr electrode was characterized systematically and the effects of initial pH, initial LEV concentration, aeration volume, voltage, and electrolyte concentration on the degradation efficiency were investigated. Results showed that more than 90% LEV was degraded and the energy consumption was 20.12 kWh/g LEV under conditions of pH 7, 6 V voltage, 2.0 L/min aeration volume, 20 mg/L initial LEV concentration, and 7 mM concentration of electrolyte (Na₂SO₄). A possible electrochemical oxidation pathway of LEV by the CPU/PPy/Gr electrode was proposed. In addition, the biotoxicity of LEV and its oxidation products was calculated using ECOSAR (Ecological Structure Activity Relationships) program in EPISuite. Toxicity evaluation using luminescent bacteria showed that the toxicities of some intermediates were higher than the parent compound. But the toxicity of degradation processes for LEV was effective decreasing. A possible reactive mechanism in the three-dimensional reactor was also recommended. In brief, the prepared CPU/PPy/Gr particle electrode constitutes an insight into the promising practical application in the wastewater treatment.
Show more [+] Less [-]Treatment of Simulated Steel Pickling Waste Liquor by Electrochemical Synthesis of Fe3O4
2020
Huang, Guangtuan | Chen, Jingwen | Gao, Shuangshuang
Due to the serious pollution and great harm of steel pickling waste liquor, the treatment of the waste liquor with high concentration of iron ion has been a problem in a lot of countries around the world. A simple electrochemical method is proposed for recovering iron from steel pickling waste liquor with graphite plates as electrodes. This study investigated the effects of reaction parameters on the concentration of residual total iron (TFe) in steel pickling waste liquor, including initial pH, reaction temperature, electrode distance, current density, and electrolytic time. Under the optimal reaction condition, the removal efficiency of TFe was 99.98%. The obtained precipitates were measured by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. It was found that the precipitates were high purity of Fe₃O₄ with small amount of γ-Fe₂O₃. This method will provide an effective and potential solution for resource recycling of steel pickling waste liquor.
Show more [+] Less [-]A novel electrocoagulation electrode configuration for the removal of total organic carbon from primary treated municipal wastewater
2020
Hawari, Alaa H. | Alkhatib, Afnan M. | Hafiz, MhdAmmar | Das, Probir
In this paper, the removal of total organic carbon (TOC) from a primary treated municipal wastewater using a new electrode configuration in electrocoagulation was evaluated. The used electrode configuration induces a dielectrophoretic (DEP) force by using an asymmetrical aluminum electrode with an alternating current power supply. The impact of applied current, electrolysis time, and interelectrode distance on the removal efficiency of TOC were evaluated. The experimental results showed that the maximum removal efficiency of TOC was obtained at 30 min electrolysis time, 600 mA applied current, and 0.5 cm interelectrode distance. Under these operating conditions, the TOC removal was 87.7% compared to 80.5% using symmetrical aluminum electrodes with no DEP effect. The energy consumption at the selected operating conditions was 3.92 kWh/m³. The experimental results were comparable with the simulation results done by COMSOL Multiphysics software.
Show more [+] Less [-]Human exposure to fluoride from tea (Camellia sinensis) in a volcanic region—Canary Islands, Spain
2020
Rodríguez, Inmaculada | Burgos, Antonio | Rubio, Carmen | Gutiérrez, Angel J. | Paz, Soraya | Rodrigues da Silva Júnior, Flavio M. | Hardisson, Arturo | Revert, Consuelo
Fluoride is highly present in the environment, especially in water and its derivatives. Excessive fluoride contribution to diet poses a health risk. Tea leaves accumulate fluoride and the consumption of tea (Camellia sinensis) could pose a risk to human by the excessive fluoride intake. Ninety tea samples were analyzed by potentiometry using a selective fluoride ion electrode. Mixed tea samples (2.82 ± 1.11 mg/L) and black tea samples (2.28 ± 0.79 mg/L) recorded the highest fluoride levels. The contribution of drinking water is important for increasing fluoride levels in teas. The daily consumption of two cups (250 mL per cup) of mixed and black teas prepared with La Laguna tap water does pose a health risk for children (4–8 years old) because of the high contribution percentages (74.4% and 63.6%, respectively) of the Tolerable Upper Intake Level set in 2.5 mg/day by the EFSA (European Food Safety Authority). A minor consumption in children (4–8 years old) and adults during pregnancy is advisable.
Show more [+] Less [-]Simultaneous bioelectricity generation from cost-effective MFC and water treatment using various wastewater samples
2020
Naik, Sweta | Jujjavarappu, Satya Eswari
Worldwide, the requirement of electrical energy has increased with an increase in population. Thus, there is a need to develop an alternative source of sustainable energy, such as microbial fuel cell (MFC). MFC is a better option of energy generation and can provide a renewable resource which utilizes wastewater into power by the help of microorganisms. MFC is one of the advanced methods for treating wastewater and simultaneously producing current and voltage. Dual-chambered MFC was prepared using two plastic boxes (500 ml) by using wastewater as an anolyte. Different types of mediators are used in MFC including methylene blue, potassium ferricyanide, and EDTA to facilitate and higher the efficiency of electron transfer from the MFC to the electrode. Maximum OCV and current output of sample 1 (Budha Talab pond water) were 0.86 V and 75.1 mA and of sample 2 (Jaypee cement plant) were 1.42 V and 122 mA. The maximum current output of sample 3 (sugar industry, sewage waste, NIT canteen) was 1.3 V. Various physiochemical parameters such as dissolved oxygen (DO), biochemical oxygen demand (BOD), and chemical oxygen demand (COD) were analyzed which affect the power output. The obtained result concluded that wastewater should be feed at a certain time interval to avoid the loss of substrate for organisms in the anodic chamber which lead to the death of the microorganism. Among all, sugar industry wastewater has a high potential for power generation as their physiochemical results are suitable for better power output.
Show more [+] Less [-]Novel Electrochemical Sensor Based on Nylon 6,6-Modified Graphite HB Pencil Electrode for Chlorothalonil Determination by Differential Pulse Cathodic Stripping Voltammetry
2020
Thanalechumi, Paramalinggam | Yusoff, Abdull Rahim Mohd | Yusop, Zulkifli
Mercury-based electrode was the choice of electrode material for many years, and it has been extensively used in voltammetry studies. Nonetheless, alternative electrode materials are highly preferred in voltammetry studies due to the toxicity of mercury. This work introduces a novel green sensor, nylon 6,6-modified graphite HB pencil electrode (Nyl-MHBPE) as electrochemical method for chlorothalonil determination by differential pulse cathodic stripping voltammetry (DPCSV). The Nyl-MHBPE was significantly improved electroactivity towards the reduction of chlorothalonil, under the optimal conditions (at pH 8.0). It was clearly observed that nylon 6,6 revealed as an efficient modifier for enhancing stripping signal for voltammetric analysis. Moreover, the developed sensor showed great feature such as a remarkably low detection limit in nanomolar level (0.94 × 10⁻⁸ M) with a linear range from 1 to 26 × 10⁻⁷ M. It presented excellent repeatability with high sensitivity and selectivity. Besides, analysis of chlorothalonil in real water samples was successfully carried out with good recovery values (92.5–103%) and relative standard deviation (RSD) values < 2.2%. The performance of Nyl-MHBPE was also compared to bare pencil electrode (HBPE). Another significant feature of this work is that the conductivity properties of the Nyl-MHBPE were superior as compared to hanging mercury drop electrode (HMDE). The present study provides admirable merits that make the Nyl-MHBPE selected as a promising electrochemical sensor to perform routine analysis of chlorothalonil.
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