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Semi-volatile organic compounds in infant homes: Levels, influence factors, partitioning, and implications for human exposure
2019
Li, Hai-Ling | Liu, Li-Yan | Zhang, Zi-Feng | Ma, Wanli | Sverko, Ed | Zhang, Zhi | Song, Wei-Wei | Sun, Yu | Li, Yi-Fan
While infants are developing, they are easily affected by toxic chemicals existing in their environments, such as semi-volatile organic compounds (SVOCs): phthalates, polycyclic aromatic hydrocarbons (PAHs), polybrominated diphenyl ethers (PBDEs), and organophosphate esters (OPEs). However, the specific living environment of infants, including increased plastic products and foam floor mats, may increase the presence of these chemicals. In this study, 68 air, dust, and window film samples were collected from homes, with 3- to 6-month-old infant occupants, to analyze phthalates, PAHs, PBDEs, and OPEs. High detection rates and concentrations suggest that these SVOCs are widespread in infant environments and are associated with cooking methods, smoking habits, the period of time after decoration, and room floors. The partitioning behavior of SVOCs indicates that the logarithms of the dust/gas-phase air partition coefficient (logKD) and the window film/gas-phase air partition coefficient (logKF) in homes are not at an equilibrium state when the logarithm of the octanol/air partition coefficient (logKOA) is less than 8 or greater than 11. Considering the 3 exposure routes, ingestion and dermal absorption have become the main routes of infant exposure to phthalates and OPEs, and ingestion and inhalation have become the dominant routes of exposure to PAHs and PBDEs. The total carcinogenic risk of SVOCs, which have carcinogenic toxicities, via ingestion and dermal absorption for infants in homes exceeds the acceptable value, suggesting that the current levels of these SVOCs in homes might pose a risk to infant health.
Show more [+] Less [-]Perfluoroalkyl acids and their precursors in indoor air sampled in children's bedrooms
2017
Winkens, Kerstin | Koponen, Jani | Schuster, Jasmin | Shoeib, Mahiba | Vestergren, Robin | Berger, Urs | Karvonen, Anne M. | Pekkanen, Juha | Kiviranta, Hannu | Cousins, Ian T.
The contamination levels and patterns of perfluoroalkyl acids (PFAAs) and their precursors in indoor air of children's bedrooms in Finland, Northern Europe, were investigated. Our study is among the most comprehensive indoor air monitoring studies (n = 57) and to our knowledge the first one to analyse air in children's bedrooms for PFASs (17 PFAAs and 9 precursors, including two acrylates, 6:2 FTAC and 6:2 FTMAC). The most frequently detected compound was 8:2 fluorotelomer alcohol (8:2 FTOH) with the highest median concentration (3570 pg/m3). FTOH concentrations were generally similar to previous studies, indicating that in 2014/2015 the impact of the industrial transition had been minor on FTOH levels in indoor air. However, in contrast to earlier studies (with one exception), median concentrations of 6:2 FTOH were higher than 10:2 FTOH. The C8 PFAAs are still the most abundant acids, even though they have now been phased out by major manufacturers. The mean concentrations of FOSE/As, especially MeFOSE (89.9 pg/m3), were at least an order of magnitude lower compared to previous studies. Collectively the comparison of FTOHs, PFAAs and FOSE/FOSAs with previous studies indicates that indoor air levels of PFASs display a time lag to changes in production of several years. This is the first indoor air study investigating 6:2 FTMAC, which was frequently detected (58%) and displayed some of the highest maximum concentrations (13 000 pg/m3). There were several statistically significant correlations between particular house and room characteristics and PFAS concentrations, most interestingly higher EtFOSE air concentrations in rooms with plastic floors compared to wood or laminate.
Show more [+] Less [-]Gaseous pollutants on rural and urban nursery schools in Northern Portugal
2016
Nunes, R.A.O. | Branco, P.T.B.S. | Alvim-Ferraz, M.C.M. | Martins, F.G. | Sousa, S.I.V.
Indoor air quality in nursery schools is different from other schools and this has been largely ignored, particularly in rural areas. Urban and rural nursery schools have different environmental characteristics whose knowledge needs improvement. Thus, this study aimed to evaluate continuously the concentrations of CO2, CO, NO2, O3, CH2O and total VOC in three rural nursery schools and one urban, being the only one comparing urban and rural nurseries with continuous measurements, thus considering occupation and non-occupation periods. Regarding CO2, urban nursery recorded higher concentrations (739–2328 mg m⁻³) than rural nurseries (653–1078 mg m⁻³). The influence of outdoor air was the main source of CO, NO2 and O3 indoor concentrations. CO and NO2 concentrations were higher in the urban nursery and O3 concentrations were higher in rural ones. CH2O and TVOC concentrations seemed to be related to internal sources, such as furniture and flooring finishing and cleaning products.
Show more [+] Less [-]Assessment of vertical element distribution in street canyons using the moss Sphagnum girgensohnii: A case study in Belgrade and Moscow cities
2016
Goryainova, Zoya | Vuković, Gordana | Uros̆ević, Mira Aničić | Vergel, Konstantin | Ostrovnaya, Tatyana | Frontasyeva, Marina | Zechmeister, Harald
Sphagnum girgensohnii moss bags were used to study the small-scale vertical distribution of some major and trace elements in different types of street canyons (regular, deep and avenue types) in Belgrade and Moscow urban area. The exposure time was 10 weeks during the summer of 2011. The exposure of moss bags was at three different levels to test differences in deposition patterns according to height. The differences between the street and off-street side in the vertical element distribution in Moscow were tested too. The concentration of 25 major and trace elements in moss was determined by instrumental neutron activation analysis. The results showed that the accumulation of elements in the exposed moss bags were higher in deep and regular street canyons in comparison to that of the avenue type, the latter even with a higher traffic flow. The element concentrations were the highest at the lowest heights compared to those of the upper floors. For most determined elements the concentrations were lower on the off-street avenue side compared to the on-street side for all heights of moss exposure. The results obtained indicate that S. girgensohnii is sensitive to small-scale variations of the total concentrations of elements.
Show more [+] Less [-]Concentrations of carbon monoxide in indoor and outdoor air of Ghalyun cafes
2015
Fazlzadeh, Mehdi | Rostami, Roohollah | Hazrati, Sadegh | Rastgu, Ali
Indoor and outdoor carbon monoxide (CO) concentrations were measured in 68 Ghalyun cafes in Ardabil City of Iran. One hour sampling was performed in each location and hourly mean concentrations were reported. Respective mean concentrations of CO in indoor and outdoor air were 24.75±17.17 and 2.65±1.33 ppm with an average indoor to outdoor air concentration ratio of 13.3±13.1. Within the variables studied; type of the tobacco smoked, location of the cafe inside the building, and utilizing mechanical ventilator, respectively, were recognized as the most influential factors controlling CO concentrations in Ghalyun cafes (p<0.05). 73.5% of workers (27.3 and 95.7% of cafes located on ground floors and basements, respectively) were exposed to higher levels of CO than the corrected OEL–TWA (Occupational Exposure Limit) of 10.4 ppm.
Show more [+] Less [-][What is the true diffusion of pollutants through the soil surface or the cellar floor: Flux chamber measurings]
1993
Wille, E.
[Diffusion of volatile organic compounds through concrete floors]
1993
Kirkegaard, C. | Holm, J.
Comparison Between Industrial–Urban and Rural Particle Stations in a Ceramic Cluster (NE, Spain)
2011
Vicente, Ana Belen | Sanfeliu, Teofilo | Jordan, Manuel Miguel
Since the beginning of the twentieth century, the province of Castellón, in eastern Spain, has been one of the most important areas of floor and wall tile production on both a national and worldwide scale. As a result of this sector’s productive rate of development (in the 1970–2005 interval), a series of pollution-producing chemical substances has been introduced into the atmosphere. The objective of this study is the comparison between industrial–urban and rural zones in this province, with the goal of establishing the causes of the contamination in order to apply corrective measures upon the different emission sources. Sustainable development is sought after to guarantee that, in the future, the environmental quality parameters fall within legal limits, ensuring the population’s well-being as well as conserving natural ecosystems and material assets. Total suspended particles and PM10 are the parameters studied. The reason for choosing this pollutant type is because particulate matter may present a much higher potential risk despite its low representativeness as compared to the gas pollutant’s group. A positive correlation between high particle concentrations and deterioration in public health has been shown in recent studies. The elements As, Cd, Ni, and Pb in PM10 were also analyzed to determine the toxicity of these particles. This study has demonstrated the different behaviors of the parameters studied at different types of stations (industrial–urban and rural), leading to the conclusion that anthropogenic factors are very important in the area studied and that they determine the area’s air quality to a great extent.
Show more [+] Less [-]Emissions of selected brominated flame retardants from consumer materials: the effects of content, temperature, and timescale
2018
Sun, Jianqiang | Chen, Qiong | Han, Ying | Zhou, Huabiao | Zhang, Anping
The ubiquitous presence of brominated flame retardants (BFRs) in indoor air, dust, and even in human tissue could be attributed to their emissions from BFR-containing products. Nevertheless, the emission behavior of BFRs, especially novel BFRs from consumer materials, to the indoor environment has still not been well understood. To evaluate the effects of chemical content, temperature, and time on the emissions of BFRs, we used a batch of small glass chambers to conduct emission tests on carpet, computer casings, sound insulation, circuit boards, decorative laminate, and PVC floors at temperatures from 20 to 80 °C, as well as different emission times of up to 35 days. Seven BFRs were extracted from the tested materials with contents ranging from 50 to 35,803 μg g⁻¹, and four BFRs were detected with emission rates between 5.9 and 418 pg g⁻¹ h⁻¹ at room temperature (20 °C); 1,2,5,6,9,10-hexabromocyclododecane (HBCD) was considered to be the dominant compound, which was found in and could be emitted from all of the tested materials. Emission rates are significantly and positively correlated with both the contents of tested materials and the elevated temperature. These results indicate that BFR-containing products have the potential to be a major source of indoor contamination.
Show more [+] Less [-][A new method for measurement of intrusion of gaseous compounds from polluted soil to the in-door atmosphere]
2002
Fuglsang, K.