Two fly ashes from municipal solid waste incineration were selected to study their heavy metal leaching behavior. The main purpose of this research is to investigate the characteristics of fly ashes and compare the leaching of heavy metals in different leaching environment. pH and acid neutralization capacity analysis showed that fly ashes were highly alkaline. Fly ashes also contained a variety of heavy metals including Pb, Cu, Cr, Zn, Cd and Ni etc. Leaching studies showed that the alkalinity of fly ashes raised the pH of leaching solution from acidic to basic. Ni, Cu and Zn were strongly bound to ashes and manifested low leaching. In contrast, Cr and Cd had high mobility but their leaching was inhibited by the low solubility of carbonate Cr and Cd. Pb was highly leachable in the alkaline environment with concentration in the leaching solution reached as high as 9.74 mg/L. In addition, the presence of EDTA in the environment also increased leaching. Pb concentration was raised to 16.63 mg/L. This could be attributed to the chelating capacity of EDTA which means that the presence of organics in natural environment should be taken into consideration.

Although the Indian population is largely vegetarian, not much attention has been given to the cultivation of vegetables, as compared to other crops like cereals, pulses and oil seeds. Therefore, the present study was conducted on two leafy vegetables, spinach (Spanacia oleracea L.) and methi (Trigonella foenum graecum L.) commonly grown in Aligarh, as the two popular vegetables of Indian diet. The study was conducted for two successive years and during the first year, phosphorus and fly ash interactions with a uniform dose of nitrogen and potassium on both vegetables was observed. During the second year, while keeping nitrogen and phosphorus uniform, potassium and fly ash combinations were studied again with both vegetables, to determine the optimum dose of inorganic fertilizers and fly ash combination. It was observed that fly ash applied at the rate of 15 t ha-1 along with N40P15K20, proved optimum for spinach while in the case of methi, N20P30K40 + FA10 was sufficient. Therefore, both vegetables can safely be grown with 10 to 15 t ha-1 of fly ash and a comparatively lower quantity of NPK.